Academic session 2026-27, Chapter 4 in the current curriculum.
Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter The d-and f-Block Elements. This page offers a step-by-step solution to the specific question from Exercise 2, Question 11:
Explain giving reasons:
(i) Transition metals and many of their compounds show paramagnetic behaviour.
(ii) The enthalpies of atomisation of the transition metals are high.
(iii) The transition metals generally form coloured compounds.
(iv) Transition metals and their many compounds act as good catalyst.
. With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.Explain giving reasons:
(i) Transition metals and many of their compounds show paramagnetic behaviour.
(ii) The enthalpies of atomisation of the transition metals are high.
(iii) The transition metals generally form coloured compounds.
(iv) Transition metals and their many compounds act as good catalyst.
(i) Transition metals show paramagnetic behaviour. Paramagnetism arises due to the presence of unpaired electrons with each electron having a magnetic moment associated with its spin angular momentum and orbital angular momentum. However, in the first transition series, the orbital angular momentum is quenched. Therefore, the resulting paramagnetism is only because of the unpaired electron.
(ii) Transition elements have high effective nuclear charge and a large number of valence electrons. Therefore, they form very strong metallic bonds. As a result, the enthalpy of atomization of transition metals is high.
(iii) Most of the complexes of transition metals are coloured. This is because of the absorption of radiation from visible light region to promote an electron from one of the d-orbitals to another. In the presence of ligands, the d-orbitals split up into two sets of orbitals having different energies. Therefore, the transition of electrons can take place from one set to another. The energy required for these transitions is quite small and falls in the visible region of radiation. The ions of transition metals absorb the radiation of a particular wavelength and the rest is reflected, imparting colour to the solution.
(iv) The catalytic activity of the transition elements can be explained by two basic facts.
(a) Owing to their ability to show variable oxidation states and form complexes, transition metals form unstable intermediate compounds. Thus, they provide a new path with lower activation energy, Ea, for the reaction.
(b) Transition metals also provide a suitable surface for the reactions to occur.
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
| Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate/mol L - 1 min - 1 |
| I | 0.1 | 0.1 |
2.0 × 10 - 2 |
| II | -- | 0.2 |
4.0 × 10 - 2 |
| III | 0.4 | 0.4 | -- |
| IV | -- | 0.2 |
2.0 × 10 - 2 |
NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:
Stay updated with our latest educational content and study tips
It’s not about starting over if you took a break to care for children, take care of yourself, be healthy or for any other reason. This is a realistic strategy for the recovery of skills, selection of the right job, and overcoming the resume problem. One year, three years or 10 years of a career … Read more
Read MoreThere’s no need to score 95% or achieve a JEE/NEET rank. You don’t need to score 95% or rank in JEE/NEET to build a solid career. A candid and pragmatic guide to the routes that actually work for students who have an average mark and what to do when faced with the options. If … Read more
Read MoreAI tools, online platforms that are much cheaper than coaching centres and the changing idea of what “structure” even means have upended this argument more in the past two years than in the decade preceding it. Here’s what is really the case for 2026 – and what has actually stayed the same. If you look … Read more
Read MoreStarting to make a new career after 30 isn’t a start from scratch. Marketing, teaching, financial, retail, healthcare, sales and other professionals can pursue careers in technology by applying the existing knowledge and skills they have acquired to new technology skills. There are various ways to enter the technology industry, such as in IT support, … Read more
Read MoreCalculate percentage from obtained marks and total marks.
Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 2 , Question 11: Explain giving reasons: (i) Transition metals and many of their compounds show paramagnetic behav....
Fresh educational articles and updates.
Most-read articles from SaralStudy.
Fast access to frequently used study resources.
Recently viewed articles based on SaralStudy activity.
Comments
Very nice it is very helpful for us
Nice explanation
Nice explanation
ðŸâÂðŸâÂ
Doubt cleared
nice explanation ðŸËÆðŸËÅ
Well explained.....