Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter Haloalkanes and Haloarenes. This page offers a step-by-step solution to the specific question from Exercise 2, Question 16: . With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.
Arrange the compounds of each set in order of reactivity towards SN2 displacement:
(i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 3-Bromo-2- methylbutane
(iii) 1-Bromobutane, 1-Bromo-2,2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-methylbutane.
(i)
An SN2 reaction involves the approaching of the nucleophile to the carbon atom to which the leaving group is attached. When the nucleophile is sterically hindered, then the reactivity towards SN2 displacement decreases. Due to the presence of substituents, hindrance to the approaching nucleophile increases in the following order.
1-Bromopentane < 2-bromopentane < 2-Bromo-2-methylbutane
Hence, the increasing order of reactivity towards SN2 displacement is:
2-Bromo-2-methylbutane < 2-Bromopentane < 1-Bromopentane
(ii)
Since steric hindrance in alkyl halides increases in the order of 1° < 2° < 3°, the increasing order of reactivity towards SN2 displacement is 3° < 2° < 1°.
Hence, the given set of compounds can be arranged in the increasing order of their reactivity towards SN2 displacement as:
2-Bromo-2-methylbutane < 2-Bromo-3-methylbutane < 1-Bromo-3-methylbutane
[2-Bromo-3-methylbutane is incorrectly given in NCERT]
(iii)
The steric hindrance to the nucleophile in the SN2 mechanism increases with a decrease in the distance of the substituents from the atom containing the leaving group. Further, the steric hindrance increases with an increase in the number of substituents. Therefore, the increasing order of steric hindrances in the given compounds is as below:
1-Bromobutane < 1-Bromo-3-methylbutane < 1-Bromo-2-methylbutane
< 1-Bromo-2, 2-dimethylpropane
Hence, the increasing order of reactivity of the given compounds towards SN2 displacement is:
1-Bromo-2, 2-dimethylpropane < 1-Bromo-2-methylbutane < 1-Bromo-3- methylbutane < 1-Bromobutane
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
| Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate/mol L - 1 min - 1 |
| I | 0.1 | 0.1 |
2.0 × 10 - 2 |
| II | -- | 0.2 |
4.0 × 10 - 2 |
| III | 0.4 | 0.4 | -- |
| IV | -- | 0.2 |
2.0 × 10 - 2 |
NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:
Stay updated with our latest educational content and study tips
Government jobs continue to be one of the most popular employment options in India because of their job security, regular salary, pension benefits, and promotion prospects. However, one of the most frequent doubts of aspirants is age eligibility. Countless candidates are discouraged from applying for Government positions – or even from preparing for them – … Read more
Read MoreAfter preparation for NEET and JEE, students inclined towards studying under state education boards find themselves a step behind the CBSE students. The syllabus, question pattern and level of idea of these national entrance exams varies widely from most state board syllabus. But with the correct approach, students taking the state board can hold their … Read more
Read MoreInterest is one of the most significant ideas in maths and financial calculations. It is very common in banking, loan applications, investments, saving account and competitive exams. Simple Interest and Compound Interest make it easier to find out how much more is earned and/or paid on a principal during the period of time. These Interest … Read more
Read MoreIn 2026, students, professionals, and job seekers must have a high level of spoken English. Spoken English is a beginner level course to enhance learners’ communication skills in English, their pronunciation, vocabulary, grammar structure and confidence in speaking English fluently. Today, the emphasis of spoken English courses is placed on actual conversations, everyday speech practice … Read more
Read MoreWelcome to the NCERT Solutions for Class 12 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 2 , Question 16: Arrange the compounds of each set in order of reactivity towards SN2 displacement: (i) 2-Bromo-2-....
Comments
Good job for stidentsr
A useful information has been provided unto me, thank so much