What is shape selective catalysis? | Class 12 Chemistry Chapter Surface Chemistry, Surface Chemistry NCERT Solutions

How are colloids classified on the basis of

(i) Physical states of components

(ii) Nature of dispersion medium and

(iii) Interaction between dispersed phase and dispersion medium?

What modification can you suggest in the Hardy-Schulze law?

Why are powdered substances more effective adsorbents than their crystalline forms?

Why is adsorption always exothermic?

What are the factors which influence the adsorption of a gas on a solid?

Give four examples of heterogeneous catalysis.

What is demulsification? Name two demulsifiers.

Comment on the statement that "colloid is not a substance but a state of substance".

Explain the terms with suitable examples:

(i) Alcosol

(ii) Aerosol

(iii) Hydrosol

Give reason why a finely divided substance is more effective as an adsorbent.

How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

Give simple chemical tests to distinguish between the following pairs of compounds.

(i) Propanal and Propanone

(ii) Acetophenone and Benzophenone

(iii) Phenol and Benzoic acid

(iv) Benzoic acid and Ethyl benzoate

(v) Pentan-2-one and Pentan-3-one

(vi) Benzaldehyde and Acetophenone

(vii) Ethanal and Propanal

A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.

A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL^-1, then what shall be the molarity of the solution?

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂ pressure at 298 K.

Calculate the mass of a non-volatile solute (molar mass 40 g mol^-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.

Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.

How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na₂CO₃ and NaHCO₃ containing equimolar amounts of both?

If NaCl is doped with 10^-3mol % of SrCl₂, what is the concentration of cation vacancies?

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂ pressure at 298 K.

What are nucleic acids? Mention their two important functions.

What are the different oxidation states exhibited by the lanthanoids?

The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:

Mention the conditions required to maximise the yield of ammonia.

Ionic solids conduct electricity in molten state but not in solid state. Explain.

Describe the oxidising action of potassium dichromate and write the ionicequations for its reaction with:

(i) iodide

(ii) iron

(II) solution and

(iii) H₂S

What type of solids are electrical conductors, malleable and ductile?

Write the structure of the major organic product in each of the following reactions:

Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.