One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10-10 m
Volume of hydrogen atom = 4/3 π r3
= 4/3 x 22/7 x (0.5 x 10-10)3
= 0.524 x 1030 m3
1 mole of hydrogen contains 6.023 × 1023 hydrogen atoms.
∴ Volume of 1 mole of hydrogen atoms = 6.023 × 1023 × 0.524 × 10-30
= 3.16 × 10-7 m3
Molar volume of 1 mole of hydrogen atoms at STP,
Vm = 22.4 L = 22.4 × 10-3 m3
∴ Vm / Va = 22.4 x 10-3 / 3.16 × 10-7 = 7.08 × 104
Hence, the molar volume is 7.08 × 104 times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
When the planet Jupiter is at a distance of 824.7 million kilometers from the Earth, its angular diameter is measured to be 35.72" of arc. Calculate the diameter of Jupiter.
The photograph of a house occupies an area of 1.75 cm2 on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m2. What is the linear magnification of the projector-screen arrangement?
It is a well known fact that during a total solar eclipse the disk of the moon almost completely covers the disk of the Sun. From this fact and from the information you can gather from examples 2.3 and 2.4, determine the approximate diameter of the moon.
Fill in the blanks
(a) The volume of a cube of side 1 cm is equal to.....m3
(b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ... (mm)2
(c) A vehicle moving with a speed of 18 km h–1covers....m in 1 s
(d) The relative density of lead is 11.3. Its density is ....g cm–3 or . ...kg m–3.
Explain this common observation clearly : If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train's motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you).
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
On a long horizontally moving belt (Fig. 3.26), a child runs to and fro with a speed 9 km h-1 (with respect to the belt) between his father and mother located 50 m apart on the moving belt. The belt moves with a speed of 4 km h-1. For an observer on a stationary platform outside, what is the
(a) speed of the child running in the direction of motion of the belt ?.
(b) speed of the child running opposite to the direction of motion of the belt ?
(c) time taken by the child in (a) and (b) ? Which of the answers alter if motion is viewed by one of the parents?
(Figure 3.26)
State if each of the following statements is true or false. Give reasons for your answer.
(a) In an elastic collision of two bodies, the momentum and energy of each body is conserved.
(b) Total energy of a system is always conserved, no matter what internal and external forces on the body are present.
(c) Work done in the motion of a body over a closed loop is zero for every force in nature.
(d) In an inelastic collision, the final kinetic energy is always less than the initial kinetic energy of the system.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Read each statement below carefully and state, with reasons, if it is true or false:
(a) The net acceleration of a particle in circular motion is always along the radius of the circle towards the centre
(b) The velocity vector of a particle at a point is always along the tangent to the path of the particle at that point
(c) The acceleration vector of a particle in uniform circular motion averaged over one cycle is a null vector
A body is initially at rest. It undergoes one-dimensional motion with constant acceleration. The power delivered to it at time t is proportional to
(i) t½ (ii) t (iii) t3/2 (iv) t2
You have learnt that a travelling wave in one dimension is represented by a function y = f (x, t) where x and t must appear in the combination x - v t or x + v t, i.e. y = f (x ± v t). Is the converse true? Examine if the following functions for y can possibly represent a travelling wave:
(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)
A train, standing in a station-yard, blows a whistle of frequency 400 Hz in still air. The wind starts blowing in the direction from the yard to the station with at a speed of 10 m s-1. What are the frequency, wavelength, and speed of sound for an observer standing on the station's platform? Is the situation exactly identical to the case when the air is still and the observer runs towards the yard at a speed of 10 m s-1? The speed of sound in still air can be taken as 340 m s-1.
Read each statement below carefully and state, with reasons and examples, if it is true or false:
A scalar quantity is one that
(a) is conserved in a process
(b) can never take negative values
(c) must be dimensionless
(d) does not vary from one point to another in space
(e) has the same value for observers with different orientations of axes
A pipe 20 cm long is closed at one end. Which harmonic mode of the pipe is resonantly excited by a 430 Hz source? Will the same source be in resonance with the pipe if both ends are open? (Speed of sound in air is 340 m s-1).
Given a + b + c + d = 0, which of the following statements are correct:
(a) a, b, c, and d must each be a null vector,
(b) The magnitude of (a + c) equals the magnitude of (b+ d),
(c) The magnitude of a can never be greater than the sum of the magnitudes of b, c, and d,
(d) b + c must lie in the plane of a and d if a and d are not collinear, and in the line of a and d, if they are collinear?