One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10-10 m
Volume of hydrogen atom = 4/3 π r3
= 4/3 x 22/7 x (0.5 x 10-10)3
= 0.524 x 1030 m3
1 mole of hydrogen contains 6.023 × 1023 hydrogen atoms.
∴ Volume of 1 mole of hydrogen atoms = 6.023 × 1023 × 0.524 × 10-30
= 3.16 × 10-7 m3
Molar volume of 1 mole of hydrogen atoms at STP,
Vm = 22.4 L = 22.4 × 10-3 m3
∴ Vm / Va = 22.4 x 10-3 / 3.16 × 10-7 = 7.08 × 104
Hence, the molar volume is 7.08 × 104 times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
When the planet Jupiter is at a distance of 824.7 million kilometers from the Earth, its angular diameter is measured to be 35.72" of arc. Calculate the diameter of Jupiter.
The photograph of a house occupies an area of 1.75 cm2 on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m2. What is the linear magnification of the projector-screen arrangement?
It is a well known fact that during a total solar eclipse the disk of the moon almost completely covers the disk of the Sun. From this fact and from the information you can gather from examples 2.3 and 2.4, determine the approximate diameter of the moon.
Fill in the blanks
(a) The volume of a cube of side 1 cm is equal to.....m3
(b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ... (mm)2
(c) A vehicle moving with a speed of 18 km h–1covers....m in 1 s
(d) The relative density of lead is 11.3. Its density is ....g cm–3 or . ...kg m–3.
Explain this common observation clearly : If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train's motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you).
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
For the wave described in Exercise 15.8, plot the displacement (y) versus (t) graphs for x = 0, 2 and 4 cm. What are the shapes of these graphs? In which aspects does the oscillatory motion in travelling wave differ from one point to another: amplitude, frequency or phase?
Figures 14.29 correspond to two circular motions. The radius of the circle, the period of revolution, the initial position, and the sense of revolution (i.e. clockwise or anti-clockwise) are indicated on each figure.
Obtain the corresponding simple harmonic motions of the x-projection of the radius vector of the revolving particle P, in each case.
In changing the state of a gas adiabatically from an equilibrium state A to another equilibrium state B, an amount of work equal to 22.3 J is done on the system. If the gas is taken from state A to B via a process in which the net heat absorbed by the system is 9.35 cal, how much is the net work done by the system in the latter case? (Take 1 cal = 4.19 J)
Fill in the blanks using the word(s) from the list appended with each statement:
(a) Surface tension of liquids generally . . . with temperatures (increases / decreases)
(b) Viscosity of gases. .. with temperature, whereas viscosity of liquids . . . with temperature (increases / decreases)
(c) For solids with elastic modulus of rigidity, the shearing force is proportional to . . . , while for fluids it is proportional to . .. (shear strain / rate of shear strain)
(d) For a fluid in a steady flow, the increase in flow speed at a constriction follows (conservation of mass / Bernoulli's principle)
(e) For the model of a plane in a wind tunnel, turbulence occurs at a ... speed for turbulence for an actual plane (greater / smaller)
An aircraft executes a horizontal loop of radius 1.00 km with a steady speed of 900 km/h. Compare its centripetal acceleration with the acceleration due to gravity.
For any arbitrary motion in space, which of the following relations are true :
(a) vaverage = (1/2) (v (t1) + v (t2))
(b) vaverage = [r(t2) - r(t1) ] / (t2 – t1)
(c) v(t) = v (0) + a t
(d) r(t) = r (0) + v (0) t + (1/2) a t2
(e) aaverage =[ v (t2) - v (t1 )] /( t2 – t1)
(The ‘average’ stands for average of the quantity over the time interval t1 to t2)
The transverse displacement of a wire (clamped at both its ends) is described as :
y (x, t) = 0.06 sin(2π/3x) cos(120πt)
The mass of the wire is 6 x 10-2 kg and its length is 3m. Provide answers to the following questions:
( I ) Is the function describing a stationary wave or a travelling wave?
( ii ) Interpret the wave as a superposition of two waves travelling in opposite directions. Find the speed, wavelength and frequency of each wave.
( iii ) Calculate the wire’s tension. [X and y are in meters and t in secs]
Given below are some functions of x and t to represent the displacement (transverse or longitudinal) of an elastic wave. State which of these represent (i) a traveling wave, (ii) a stationary wave or (iii) none at all:
(a) y = 2 cos (3x) sin (10t)
(b) y = 2 underroot(x -vt)
(c) y = 3 sin (5x - 0.5t) + 4 cos (5x - 0.5t)
(d) y = cos x sin t + cos 2x sin 2t
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.