What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
Mass of nitrogen, m = 2.0 × 10-2 kg = 20 g
Rise in temperature, ΔT = 45°C
Molecular mass of N2, M = 28
Universal gas constant, R = 8.3 J mol-1 K-1
Number of moles, n = m / M
= 2.0 x 10-2 x 103 / 28 = 0.714
Molar specific heat at constant pressure for nitrogen, CP = 7/2R
= 7/2 x 8.3
= 29.05 J mol-1 K-1
The total amount of heat to be supplied is given by the relation:
ΔQ = nCP ΔT
= 0.714 × 29.05 × 45
= 933.38 J
Therefore, the amount of heat to be supplied is 933.38 J.
An electric heater supplies heat to a system at a rate of 100W. If system performs work at a rate of 75 Joules per second. At what rate is the internal energy increasing?
A steam engine delivers 5.4 x 108 J of work per minute and services 3.6 x 109 J of heat per minute from its boiler. What is the efficiency of the engine? How much heat is wasted per minute?
A refrigerator is to maintain eatables kept inside at 9°C. If room temperature is 36° C, calculate the coefficient of performance.
In changing the state of a gas adiabatically from an equilibrium state A to another equilibrium state B, an amount of work equal to 22.3 J is done on the system. If the gas is taken from state A to B via a process in which the net heat absorbed by the system is 9.35 cal, how much is the net work done by the system in the latter case? (Take 1 cal = 4.19 J)
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A body is initially at rest. It undergoes one-dimensional motion with constant acceleration. The power delivered to it at time t is proportional to
(i) t½ (ii) t (iii) t3/2 (iv) t2
The position-time (x-t) graphs for two children A and B returning from their school O to their homes P and Q respectively are shown in Fig. 3.19. Choose the correct entries in the brackets below;
(a) (A/B) lives closer to the school than (B/A)
(b) (A/B) starts from the school earlier than (B/A)
(c) (A/B) walks faster than (B/A)
(d) A and B reach home at the (same/different) time
(e) (A/B) overtakes (B/A) on the road (once/twice).
Read each statement below carefully and state, with reasons and examples, if it is true or false:
A scalar quantity is one that
(a) is conserved in a process
(b) can never take negative values
(c) must be dimensionless
(d) does not vary from one point to another in space
(e) has the same value for observers with different orientations of axes
The unit of length convenient on the nuclear scale is a fermi : 1 f = 10 - 15 m. Nuclear sizes obey roughly the following empirical relation : r = r0 A1/3
where r is the radius of the nucleus, A its mass number, and r0 is a constant equal to about, 1.2 f. Show that the rule implies that nuclear mass density is nearly constant for different nuclei. Estimate the mass density of sodium nucleus. Compare it with the average mass density of a sodium atom obtained in Exercise. 2.27.
Three girls skating on a circular ice ground of radius 200 m start from a point P on the edge of the ground and reach a point Q diametrically opposite to P following different paths as shown in Fig. 4.20. What is the magnitude of the displacement vector for each? For which girl is this equal to the actual length of the path skated?
A drunkard walking in a narrow lane takes 5 steps forward and 3 steps backward, followed again by 5 steps forward and 3 steps backward, and so on. Each step is 1 m long and requires 1 s. Plot the x-t graph of his motion. Determine graphically and otherwise how long the drunkard takes to fall in a pit 13 m away from the start.
Two sitar strings A and B playing the note 'Ga' are slightly out of tune and produce beats of frequency 6 Hz. The tension in the string A is slightly reduced and the beat frequency is found to reduce to 3 Hz. If the original frequency of A is 324 Hz, what is the frequency of B?
Two billiard balls each of mass 0.05 kg moving in opposite directions with speed 6 ms-1collide and rebound with the same speed. What is the impulse imparted to each ball due to the other?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]