From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Rate of diffusion of hydrogen, R1 = 28.7 cm3s-1
Rate of diffusion of another gas, R2= 7.2 cm3s-1
According to Graham's Law of diffusion, we have:
R1 / R2 = Underroot M2/M1
Where, M1 is the molecular mass of hydrogen = 2.020 g
M2 is the molecular mass of the unknown gas
∴ M2 =M1 (R1 / R2)2
=2.02 (28.7 / 7.2)2
= 32.09 g
32 g is the molecular mass of oxygen. Hence, the unknown gas is oxygen.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A SONAR (sound navigation and ranging) uses ultrasonic waves to detect and locate objects under water. In a submarine equipped with a SONAR the time delay between generation of a probe wave and the reception of its echo after reflection from an enemy submarine is found to be 77.0 s. What is the distance of the enemy submarine? (Speed of sound in water = 1450 m s-1).
A spring balance has a scale that reads from 0 to 50 kg. The length of the scale is 20 cm. A body suspended from this balance, when displaced and released, oscillates with a period of 0.6 s. What is the weight of the body?
A travelling harmonic wave on a string is described by
y(x,t) = 7.5sin [0.0050x + 12t + π/4]
(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?
(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
Does the escape speed of a body from the earth depend on
(a) the mass of the body,
(b) the location from where it is projected,
(c) the direction of projection,
(d) the height of the location from where the body is launched?
A jet airplane travelling at the speed of 500 km h-1 ejects its products of combustion at the speed of 1500 km h-1 relative to the jet plane. What is the speed of the latter with respect to an observer on ground?
For the travelling harmonic wave
y (x, t) = 2.0 cos 2π (10t - 0.0080 x + 0.35)
Where x and y are in cm and t in s. Calculate the phase difference between oscillatory motion of two points separated by a distance of
(a) 4 m,
(b) 0.5 m,
(c) λ / 2 ,
(d) 3λ / 4
Use the formula v = √ γP/ρ to explain why the speed of sound in air (a) is independent of pressure, (b) increases with temperature, (c) increases with humidity.
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
A woman starts from her home at 9.00 am, walks with a speed of 5 km h-1 on a straight road up to her office 2.5 km away, stays at the office up to 5.00 pm, and returns home by an auto with a speed of 25 km h-1. Choose suitable scales and plot the x-t graph of her motion.
A train runs along an unbanked circular track of radius 30 m at a speed of 54 km/h. The mass of the train is 106 kg. What provides the centripetal force required for this purpose - The engine or the rails? What is the angle of banking required to prevent wearing out of the rail?