From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Rate of diffusion of hydrogen, R1 = 28.7 cm3s-1
Rate of diffusion of another gas, R2= 7.2 cm3s-1
According to Graham's Law of diffusion, we have:
R1 / R2 = Underroot M2/M1
Where, M1 is the molecular mass of hydrogen = 2.020 g
M2 is the molecular mass of the unknown gas
∴ M2 =M1 (R1 / R2)2
=2.02 (28.7 / 7.2)2
= 32.09 g
32 g is the molecular mass of oxygen. Hence, the unknown gas is oxygen.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
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(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
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A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
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(a) a = 0.7x
(b) a = -200x2
(c) a = -10x
(d) a = 100x3
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y(x,t) = 7.5sin [0.0050x + 12t + π/4]
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(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
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(i) What is the frequency of the whistle for a platform observer when the train
(a) approaches the platform with a speed of 10 m s-1,
(b) recedes from the platform with a speed of 10 m s-1?
(ii) What is the speed of sound in each case? The speed of sound in still air can be taken as 340 m s-1.
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(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)
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(a) In an elastic collision of two bodies, the momentum and energy of each body is conserved.
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(c) Work done in the motion of a body over a closed loop is zero for every force in nature.
(d) In an inelastic collision, the final kinetic energy is always less than the initial kinetic energy of the system.
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(a) the mass of the body,
(b) the location from where it is projected,
(c) the direction of projection,
(d) the height of the location from where the body is launched?