From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Rate of diffusion of hydrogen, R1 = 28.7 cm3s-1
Rate of diffusion of another gas, R2= 7.2 cm3s-1
According to Graham's Law of diffusion, we have:
R1 / R2 = Underroot M2/M1
Where, M1 is the molecular mass of hydrogen = 2.020 g
M2 is the molecular mass of the unknown gas
∴ M2 =M1 (R1 / R2)2
=2.02 (28.7 / 7.2)2
= 32.09 g
32 g is the molecular mass of oxygen. Hence, the unknown gas is oxygen.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Figure 14.27 depicts four x-t plots for linear motion of a particle. Which of the plots represent periodic motion? What is the period of motion (in case of periodic motion)?
For the travelling harmonic wave
y (x, t) = 2.0 cos 2π (10t - 0.0080 x + 0.35)
Where x and y are in cm and t in s. Calculate the phase difference between oscillatory motion of two points separated by a distance of
(a) 4 m,
(b) 0.5 m,
(c) λ / 2 ,
(d) 3λ / 4
A narrow sound pulse (for example, a short pip by a whistle) is sent across a medium.
(a) Does the pulse have a definite (i) frequency, (ii) wavelength, (iii) speed of propagation?
(b) If the pulse rate is 1 after every 20 s, (that is the whistle is blown for a split of second after every 20 s), is the frequency of the note produced by the whistle equal to or 0.05 Hz?
Given below are some functions of x and t to represent the displacement (transverse or longitudinal) of an elastic wave. State which of these represent (i) a traveling wave, (ii) a stationary wave or (iii) none at all:
(a) y = 2 cos (3x) sin (10t)
(b) y = 2 underroot(x -vt)
(c) y = 3 sin (5x - 0.5t) + 4 cos (5x - 0.5t)
(d) y = cos x sin t + cos 2x sin 2t
A pipe 20 cm long is closed at one end. Which harmonic mode of the pipe is resonantly excited by a 430 Hz source? Will the same source be in resonance with the pipe if both ends are open? (Speed of sound in air is 340 m s-1).
Which of the following relationships between the acceleration a and the displacement x of a particle involve simple harmonic motion?
(a) a = 0.7x
(b) a = -200x2
(c) a = -10x
(d) a = 100x3
A train, standing at the outer signal of a railway station blows a whistle of frequency 400 Hz in still air.
(i) What is the frequency of the whistle for a platform observer when the train
(a) approaches the platform with a speed of 10 m s-1,
(b) recedes from the platform with a speed of 10 m s-1?
(ii) What is the speed of sound in each case? The speed of sound in still air can be taken as 340 m s-1.
( i ) The time period of a body having simple harmonic motion depends on the mass m of the body and the force constant k:
T =2π √m/k
A simple pendulum exhibits simple harmonic motion. Then why does the time period of a pendulum not depend upon its mass?
( ii ) For small angle oscillations, a simple pendulum exhibits simple harmonic motion ( more or less). For larger angles of oscillation, detailed analysis show that T is greater than 2π√ l/g. Explain.
( iii ) A boy with a wristwatch on his hand jumps from a helicopter. Will the wrist watch give the correct time during free fall?
( iv ) Find the frequency of oscillation of a simple pendulum that is free falling from a tall bridge.
A circular disc of mass 10 kg is suspended by a wire attached to its centre. The wire is twisted by rotating the disc and released. The period of torsional oscillations is found to be 1.5 s. The radius of the disc is 15 cm. Determine the torsional spring constant of the wire.
(Torsional spring constant α is defined by the relation J = -α ø, where J is the restoring couple and ø¸ the angle of twist).