From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Rate of diffusion of hydrogen, R1 = 28.7 cm3s-1
Rate of diffusion of another gas, R2= 7.2 cm3s-1
According to Graham's Law of diffusion, we have:
R1 / R2 = Underroot M2/M1
Where, M1 is the molecular mass of hydrogen = 2.020 g
M2 is the molecular mass of the unknown gas
∴ M2 =M1 (R1 / R2)2
=2.02 (28.7 / 7.2)2
= 32.09 g
32 g is the molecular mass of oxygen. Hence, the unknown gas is oxygen.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A refrigerator is to maintain eatables kept inside at 9°C. If room temperature is 36° C, calculate the coefficient of performance.
It is claimed that two cesium clocks, if allowed to run for 100 years, free from any disturbance, may differ by only about 0.02 s. What does this imply for the accuracy of the standard cesium clock in measuring a time-interval of 1 s?
The piston in the cylinder head of a locomotive has a stroke (twice the amplitude) of 1.0 m. If the piston moves with simple harmonic motion with an angular frequency of 200 rad/min, what is its maximum speed?
A monkey of mass 40 kg climbs on a rope (Fig. 5.20) which can stand a maximum tension of 600 N. In which of the following cases will the rope break: the monkey
(a) climbs up with an acceleration of 6 m s-2
(b) climbs down with an acceleration of 4 m s-2
(c) climbs up with a uniform speed of 5 m s-1
(d) falls down the rope nearly freely under gravity?
(Ignore the mass of the rope).
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
A travelling harmonic wave on a string is described by
y(x,t) = 7.5sin [0.0050x + 12t + π/4]
(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?
(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
A man walks on a straight road from his home to a market 2.5 km away with a speed of 5 km h –1. Finding the market closed, he instantly turns and walks back home with a speed of 7.5 km h–1. What is the
a) magnitude of average velocity, and
b) average speed of the man over the interval of time (i) 0 to 30 min, (ii) 0 to 50 min, (iii) 0 to 40 min?
[Note: You will appreciate from this exercise why it is better to define average speed as total path length divided by time, and not as magnitude of average velocity. You would not like to tell the tired man on his return home that his average speed was zero!]
Choose the correct alternative:
(a) If the zero of potential energy is at infinity, the total energy of an orbiting satellite is negative of its kinetic/potential energy.
(b) The energy required to launch an orbiting satellite out of earth’s gravitational influence is more/less than the energy required to project a stationary object at the same height (as the satellite) out of earth’s influence.
You have learnt that a travelling wave in one dimension is represented by a function y = f (x, t) where x and t must appear in the combination x - v t or x + v t, i.e. y = f (x ± v t). Is the converse true? Examine if the following functions for y can possibly represent a travelling wave:
(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)