Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Yes.All contain the same number of the respective molecules.
No. The root mean square speed of neon is the largest.
Since the three vessels have the same capacity, they have the same volume.
Hence, each gas has the same pressure, volume, and temperature.
According to Avogadro's law, the three vessels will contain an equal number of the respective molecules. This number is equal to Avogadro's number, N= 6.023 × 1023.
The root mean square speed (vrms) of a gas of mass m, and temperature T, is given by the relation:
vrms = underroot 3kT / m
Where, k is Boltzmann constant
For the given gases, k and T are constants.
Hence vrmsdepends only on the mass of the atoms, i.e.,
vrms ∝ underroot 1/m
Therefore, the root mean square speed of the molecules in the three cases is not the same. Among neon, chlorine, and uranium hexafluoride, the mass of neon is the smallest. Hence, neon has the largest root mean square speed among the given gases.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
An electric heater supplies heat to a system at a rate of 100W. If system performs work at a rate of 75 Joules per second. At what rate is the internal energy increasing?
Figure 3.23 gives the x-t plot of a particle executing one-dimensional simple harmonic motion. (You will learn about this motion in more detail in Chapter14). Give the signs of position, velocity and acceleration variables of the particle at t = 0.3 s, 1.2 s, – 1.2 s.
(Fig 3.23)
A U-shaped wire is dipped in a soap solution, and removed. The thin soap film formed between the wire and the light slider supports a weight of 1.5 x 10-2 N (which includes the small weight of the slider). The length of the slider is 30 cm. What is the surface tension of the film?
Which of the following symptoms is likely to afflict an astronaut in space (a) swollen feet, (b) swollen face, (c) headache, (d) orientational problem?
Does the escape speed of a body from the earth depend on
(a) the mass of the body,
(b) the location from where it is projected,
(c) the direction of projection,
(d) the height of the location from where the body is launched?
Earthquakes generate sound waves inside the earth. Unlike a gas, the earth can experience both transverse (S) and longitudinal (P) sound waves. Typically the speed of S wave is about 4.0 km s-1, and that of P wave is 8.0 km s-1. A seismograph records P and S waves from an earthquake. The first P wave arrives 4 min before the first S wave. Assuming the waves travel in straight line, at what distance does the earthquake occur?
A great physicist of this century (P.A.M. Dirac) loved playing with numerical values of Fundamental constants of nature. This led him to an interesting observation. Dirac found that from the basic constants of atomic physics (c, e, mass of electron, mass of proton) and the gravitational constant G, he could arrive at a number with the dimension of time. Further, it was a very large number, its magnitude being close to the present estimate on the age of the universe (~15 billion years). From the table of fundamental constants in this book, try to see if you too can construct this number (or any other interesting number you can think of). If its coincidence with the age of the universe were significant, what would this imply for the constancy of fundamental constants?
The nearest star to our solar system is 4.29 light years away. How much is this distance in terms of parsecs? How much parallax would this star (named Alpha Centauri) show when viewed from two locations of the Earth six months apart in its orbit around the Sun?
A player throws a ball upwards with an initial speed of 29.4 m s–1. What is the direction of acceleration during the upward motion of the ball? What are the velocity and acceleration of the ball at the highest point of its motion?
Choose the x = 0 m and t = 0 s to be the location and time of the ball at its highest point, vertically downward direction to be the positive direction of x-axis, and give the signs of position, velocity and acceleration of the ball during its upward, and downward motion. To what height does the ball rise and after how long does the ball return to the player’s hands? (Take g = 9.8 m s–2 and neglect air resistance).
A train, standing at the outer signal of a railway station blows a whistle of frequency 400 Hz in still air.
(i) What is the frequency of the whistle for a platform observer when the train
(a) approaches the platform with a speed of 10 m s-1,
(b) recedes from the platform with a speed of 10 m s-1?
(ii) What is the speed of sound in each case? The speed of sound in still air can be taken as 340 m s-1.