Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Yes.All contain the same number of the respective molecules.
No. The root mean square speed of neon is the largest.
Since the three vessels have the same capacity, they have the same volume.
Hence, each gas has the same pressure, volume, and temperature.
According to Avogadro's law, the three vessels will contain an equal number of the respective molecules. This number is equal to Avogadro's number, N= 6.023 × 1023.
The root mean square speed (vrms) of a gas of mass m, and temperature T, is given by the relation:
vrms = underroot 3kT / m
Where, k is Boltzmann constant
For the given gases, k and T are constants.
Hence vrmsdepends only on the mass of the atoms, i.e.,
vrms ∝ underroot 1/m
Therefore, the root mean square speed of the molecules in the three cases is not the same. Among neon, chlorine, and uranium hexafluoride, the mass of neon is the smallest. Hence, neon has the largest root mean square speed among the given gases.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
Read each statement below carefully, and state, with reasons, if it is true or false;
(a) During rolling, the force of friction acts in the same direction as the direction of motion of the CM of the body.
(b) The instantaneous speed of the point of contact during rolling is zero.
(c) The instantaneous acceleration of the point of contact during rolling is zero.
(d) For perfect rolling motion, work done against friction is zero.
(e) A wheel moving down a perfectly frictionless inclined plane will undergo slipping (not rolling) motion.
A constant force acting on a body of mass 3.0 kg changes its speed from 2.0 m s–1 to 3.5 m s–1 in 25 s. The direction of the motion of the body remains unchanged. What is the magnitude and direction of the force?
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
During blood transfusion the needle is inserted in a vein where the gauge pressure is 2000 Pa. At what height must the blood container be placed so that blood may just enter the vein? [Use the density of whole blood from Table 10.1].
Which of the following examples represent (nearly) simple harmonic motion and which represent periodic but not simple harmonic motion?
(a) the rotation of earth about its axis.
(b) motion of an oscillating mercury column in a U-tube.
(c) motion of a ball bearing inside a smooth curved bowl, when released from a point slightly above the lower most point.
(d) general vibrations of a polyatomic molecule about its equilibrium position.
The motion of a body in simple harmonic motion is given by the displacement function,
x (t) = A cos (ωt + φ).
Given that at t = 0, the initial velocity of the body is ω cm/s and its initial position is 1 cm, calculate its initial phase angle and amplitude?
If in place of the cosine function, a sine function is used to represent the simple harmonic motion:
x = B sin (ωt + α),
calculate the body’s amplitude and initial phase considering the initial conditions given above. [Angular frequency of the particle is π/ s]
Figure 3.21 shows the x-t plot of one-dimensional motion of a particle. Is it correct to say from the graph that the particle moves in a straight line for t < 0 and on a parabolic path for t > 0? If not, suggest a suitable physical context for this graph.
The shells of crabs found around a particular coastal location in Japan seem mostly to resemble the legendary face of a Samurai. Given below are two explanations of this observed fact. Which of these strikes you as a scientific explanation ?
(a) A tragic sea accident several centuries ago drowned a young Samurai. As a tribute to his bravery, nature through its inscrutable ways immortalised his face by imprinting it on the crab shells in that area.
(b) After the sea tragedy, fishermen in that area, in a gesture of honour to their dead hero, let free any crab shell caught by them which accidentally had a shape resembling the face of a Samurai. Consequently, the particular shape of the crab shell survived longer and therefore in course of time the shape was genetically propagated. This is an example of evolution by artificial selection.
[Note : This interesting illustration taken from Carl Sagan’s ‘The Cosmos’ highlights the fact that often strange and inexplicable facts which on the first sight appear ‘supernatural’ actually turn out to have simple scientific explanations. Try to think out other examples of this kind].