Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Two trains A and B of length 400 m each are moving on two parallel tracks with a uniform speed of 72 km h–1 in the same direction, with A ahead of B. The driver of B decides to overtake A and accelerates by 1 m/s2. If after 50 s, the guard of B just brushes past the driver of A, what was the original distance between them?
During blood transfusion the needle is inserted in a vein where the gauge pressure is 2000 Pa. At what height must the blood container be placed so that blood may just enter the vein? [Use the density of whole blood from Table 10.1].
A particle is in linear simple harmonic motion between two points, A and B, 10 cm apart. Take the direction from A to B as the positive direction and give the signs of velocity, acceleration and force on the particle when it is
(a) at the end A,
(b) at the end B,
(c) at the mid-point of AB going towards A,
(d) at 2 cm away from B going towards A,
(e) at 3 cm away from A going towards B, and
(f) at 4 cm away from B going towards A.
One end of a long string of linear mass density 8.0 x 10-3 kg m-1 is connected to an electrically driven tuning fork of frequency 256 Hz. The other end passes over a pulley and is tied to a pan containing a mass of 90 kg. The pulley end absorbs all the incoming energy so that reflected waves at this end have negligible amplitude. At t = 0, the left end (fork end) of the string x = 0 has zero transverse displacement (y = 0) and is moving along positive y-direction. The amplitude of the wave is 5.0 cm. Write down the transverse displacement y as function of x and t that describes the wave on the string.
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
A rope of negligible mass is wound round a hollow cylinder of mass 3 kg and radius 40 cm. What is the angular acceleration of the cylinder if the rope is pulled with a force of 30 N? What is the linear acceleration of the rope? Assume that there is no slipping.
Precise measurements of physical quantities are a need of science. For example, to ascertain the speed of an aircraft, one must have an accurate method to find its positions at closely separated instants of time. This was the actual motivation behind the discovery of radar in World War II. Think of different examples in modern science where precise measurements of length, time, mass etc. are needed. Also, wherever you can, give a quantitative idea of the precision needed.
The blades of a windmill sweep out a circle of area A. (a) If the wind flows at a velocity v perpendicular to the circle, what is the mass of the air passing through it in time t?(b) What is the kinetic energy of the air? (c) Assume that the windmill converts 25% of the wind's energy into electrical energy, and that A = 30 m2, v = 36 km/h and the density of air is 1.2 kg m-3. What is the electrical power produced?
It is claimed that two cesium clocks, if allowed to run for 100 years, free from any disturbance, may differ by only about 0.02 s. What does this imply for the accuracy of the standard cesium clock in measuring a time-interval of 1 s?