Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Precise measurements of physical quantities are a need of science. For example, to ascertain the speed of an aircraft, one must have an accurate method to find its positions at closely separated instants of time. This was the actual motivation behind the discovery of radar in World War II. Think of different examples in modern science where precise measurements of length, time, mass etc. are needed. Also, wherever you can, give a quantitative idea of the precision needed.
The unit of length convenient on the atomic scale is known as an angstrom and is denoted by Å : 1Å = 10-10 m. The size of a hydrogen atom is about 0.5 Å what is the total atomic volume in m3 of a mole of hydrogen atoms?
Attempt to formulate your ‘moral’ views on the practice of science. Imagine yourself stumbling upon a discovery, which has great academic interest but is certain to have nothing but dangerous consequences for the human society. How, if at all, will you resolve your dilemma?
Answer the following:
(a) You are given a thread and a metre scale. How will you estimate the diameter of the thread?
(b) A screw gauge has a pitch of 1.0 mm and 200 divisions on the circular scale. Do you think it is possible to increase the accuracy of the screw gauge arbitrarily by increasing the number of divisions on the circular scale?
(c) The mean diameter of a thin brass rod is to be measured by vernier callipers. Why is a set of 100 measurements of the diameter expected to yield a more reliable estimate than a set of 5 measurements only?
A SONAR system fixed in a submarine operates at a frequency 40.0 kHz. An enemy submarine moves towards the SONAR with a speed of 360 km h-1. What is the frequency of sound reflected by the submarine? Take the speed of sound in water to be 1450 m s-1.
Write in about 1000 words a fiction piece based on your speculation on the science and technology of the twenty-second century.
A constant force acting on a body of mass 3.0 kg changes its speed from 2.0 m s–1 to 3.5 m s–1 in 25 s. The direction of the motion of the body remains unchanged. What is the magnitude and direction of the force?
A bolt of mass 0.3 kg falls from the ceiling of an elevator moving down with an uniform speed of 7 m s-1. It hits the floor of the elevator (length of the elevator = 3 m) and does not rebound. What is the heat produced by the impact? Would your answer be different if the elevator were stationary?
A student measures the thickness of a human hair by looking at it through a microscope of magnification 100. He makes 20 observations and finds that the average width of the hair in the field of view of the microscope is 3.5 mm. What is the estimate on the thickness of hair?