Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A cricketer can throw a ball to a maximum horizontal distance of 100 m. How much high above the ground can the cricketer throw the same ball?
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A metre-long tube open at one end, with a movable piston at the other end, shows resonance with a fixed frequency source (a tuning fork of frequency 340 Hz) when the tube length is 25.5 cm or 79.3 cm. Estimate the speed of sound in air at the temperature of the experiment. The edge effects may be neglected.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Ten one-rupee coins are put on top of each other on a table. Each coin has a mass m. Give the magnitude and direction of
(a) the force on the 7th coin (counted from the bottom) due to all the coins on its top,
(b) the force on the 7th coin by the eighth coin,
(c) the reaction of the 6th coin on the 7th coin.
If, in Exercise 5.21, the speed of the stone is increased beyond the maximum permissible value, and the string breaks suddenly, which of the following correctly describes the trajectory of the stone after the string breaks:
(a) the stone moves radially outwards,
(b) the stone flies off tangentially from the instant the string breaks,
(c) the stone flies off at an angle with the tangent whose magnitude depends on the speed of the particle ?
A vector has both magnitude and direction. Does it mean that anything that has magnitude and direction is necessarily a vector? The rotation of a body can be specified by the direction of the axis of rotation, and the angle of rotation about the axis. Does that make any rotation a vector?
Attempt to formulate your ‘moral’ views on the practice of science. Imagine yourself stumbling upon a discovery, which has great academic interest but is certain to have nothing but dangerous consequences for the human society. How, if at all, will you resolve your dilemma?
The speed-time graph of a particle moving along a fixed direction is shown in Fig. 3.28. Obtain the distance traversed by the particle between (a) t = 0 s to 10 s, (b) t = 2 s to 6 s.
(Fig. 3.28)
What is the average speed of the particle over the intervals in (a) and (b)?