Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Given a + b + c + d = 0, which of the following statements are correct:
(a) a, b, c, and d must each be a null vector,
(b) The magnitude of (a + c) equals the magnitude of (b+ d),
(c) The magnitude of a can never be greater than the sum of the magnitudes of b, c, and d,
(d) b + c must lie in the plane of a and d if a and d are not collinear, and in the line of a and d, if they are collinear?
A man walking briskly in rain with speed v must slant his umbrella forward making an angle θ with the vertical. A student derives the following relation between θ and v : tan θ = v and checks that the relation has a correct limit: as v → 0, θ →0, as expected. (We are assuming there is no strong wind and that the rain falls vertically for a stationary man). Do you think this relation can be correct ? If not, guess the correct relation.
A calorie is a unit of heat or energy and it equals about 4.2 J where 1J = 1 kg m2s–2. Suppose we employ a system of units in which the unit of mass equals α kg, the unit of length equals β m, the unit of time is γ s. Show that a calorie has a magnitude 4.2 α–1 β– 2 γ2 in terms of the new units.
Torques of equal magnitude are applied to a hollow cylinder and a solid sphere, both having the same mass and radius. The cylinder is free to rotate about its standard axis of symmetry, and the sphere is free to rotate about an axis passing through its centre. Which of the two will acquire a greater angular speed after a given time?
The principle of ‘parallax’ in section 2.3.1 is used in the determination of distances of very distant stars. The baseline AB is the line joining the Earth’s two locations six months apart in its orbit around the Sun. That is, the baseline is about the diameter of the Earth’s orbit ≈ 3 × 1011m. However, even the nearest stars are so distant that with such a long baseline, they show parallax only of the order of 1” (second) of arc or so. A parsec is a convenient unit of length on the astronomical scale. It is the distance of an object that will show a parallax of 1” (second) of arc from opposite ends of a baseline equal to the distance from the Earth to the Sun. How much is a parsec in terms of metres ?
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
A police van moving on a highway with a speed of 30 km h-1 fires a bullet at a thief's car speeding away in the same direction with a speed of 192 km h-1. If the muzzle speed of the bullet is 150 m s-1, with what speed does the bullet hit the thief's car ? (Note: Obtain that speed which is relevant for damaging the thief's car).
A block of mass 15 kg is placed on a long trolley. The coefficient of static friction between the block and the trolley is 0.18. The trolley accelerates from rest with 0.5 ms-2 for 20 s and then moves with uniform velocity. Discuss the motion of the block as viewed by (a) a stationary observer on the ground, (b) an observer moving with the trolley.
Read each statement below carefully and state, with reasons, if it is true or false:
(a) The net acceleration of a particle in circular motion is always along the radius of the circle towards the centre
(b) The velocity vector of a particle at a point is always along the tangent to the path of the particle at that point
(c) The acceleration vector of a particle in uniform circular motion averaged over one cycle is a null vector
The position-time (x-t) graphs for two children A and B returning from their school O to their homes P and Q respectively are shown in Fig. 3.19. Choose the correct entries in the brackets below;
(a) (A/B) lives closer to the school than (B/A)
(b) (A/B) starts from the school earlier than (B/A)
(c) (A/B) walks faster than (B/A)
(d) A and B reach home at the (same/different) time
(e) (A/B) overtakes (B/A) on the road (once/twice).