Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Two vessels have the same base area but different shapes. The first vessel takes twice the volume of water that the second vessel requires to fill upto a particular common height. Is the force exerted by the water on the base of the vessel the same in the two cases? If so, why do the vessels filled with water to that same height give different readings on a weighing scale?
A constant force acting on a body of mass 3.0 kg changes its speed from 2.0 m s–1 to 3.5 m s–1 in 25 s. The direction of the motion of the body remains unchanged. What is the magnitude and direction of the force?
Given below are some functions of x and t to represent the displacement (transverse or longitudinal) of an elastic wave. State which of these represent (i) a traveling wave, (ii) a stationary wave or (iii) none at all:
(a) y = 2 cos (3x) sin (10t)
(b) y = 2 underroot(x -vt)
(c) y = 3 sin (5x - 0.5t) + 4 cos (5x - 0.5t)
(d) y = cos x sin t + cos 2x sin 2t
Two billiard balls each of mass 0.05 kg moving in opposite directions with speed 6 ms-1collide and rebound with the same speed. What is the impulse imparted to each ball due to the other?
A vertical off-shore structure is built to withstand a maximum stress of 109 Pa. Is the structure suitable for putting up on top of an oil well in the ocean? Take the depth of the ocean to be roughly 3 km, and ignore ocean currents.
A 50 kg girl wearing high heel shoes balances on a single heel. The heel is circular with a diameter 1.0 cm. What is the pressure exerted by the heel on the horizontal floor?
Two stones are thrown up simultaneously from the edge of a cliff 200 m high with initial speeds of 15 m s–1 and 30 m s–1. Verify that the graph shown in Fig. 3.27 correctly represents the time variation of the relative position of the second stone with respect to the first. Neglect air resistance and assume that the stones do not rebound after hitting the ground. Take g = 10 m s–2. Give the equations for the linear and curved parts of the plot.
A car moving along a straight highway with a speed of 126 km h–1 is brought to a stop within a distance of 200 m. What is the retardation of the car (assumed uniform), and how long does it take for the car to stop?
A monkey of mass 40 kg climbs on a rope (Fig. 5.20) which can stand a maximum tension of 600 N. In which of the following cases will the rope break: the monkey
(a) climbs up with an acceleration of 6 m s-2
(b) climbs down with an acceleration of 4 m s-2
(c) climbs up with a uniform speed of 5 m s-1
(d) falls down the rope nearly freely under gravity?
(Ignore the mass of the rope).