Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A bat emits ultrasonic sound of frequency 1000 kHz in air. If the sound meets a water surface, what is the wavelength of (a) the reflected sound, (b) the transmitted sound? Speed of sound in air is 340 m s-1 and in water 1486 m s-1.
A person trying to lose weight (dieter) lifts a 10 kg mass, one thousand times, to a height of 0.5 m each time. Assume that the potential energy lost each time she lowers the mass is dissipated. (a) How much work does she do against the gravitational force? (b) Fat supplies 3.8 x 107 J of energy per kilogram which is converted to mechanical energy with a 20% efficiency rate. How much fat will the dieter use up?
A vector has magnitude and direction. Does it have a location in space? Can it vary with time? Will two equal vectors a and b at different locations in space necessarily have identical physical effects? Give examples in support of your answer.
A hydraulic automobile lift is designed to lift cars with a maximum mass of 3000 kg. The area of cross-section of the piston carrying the load is 425 cm2. What maximum pressure would the smaller piston have to bear?
The piston in the cylinder head of a locomotive has a stroke (twice the amplitude) of 1.0 m. If the piston moves with simple harmonic motion with an angular frequency of 200 rad/min, what is its maximum speed?
Figure 3.23 gives the x-t plot of a particle executing one-dimensional simple harmonic motion. (You will learn about this motion in more detail in Chapter14). Give the signs of position, velocity and acceleration variables of the particle at t = 0.3 s, 1.2 s, – 1.2 s.
(Fig 3.23)
“It is more important to have beauty in the equations of physics than to have them agree with experiments”. The great British physicist P. A. M. Dirac held this view. Criticize this statement. Look out for some equations and results in this book which strike you as beautiful.
The motion of a body in simple harmonic motion is given by the displacement function,
x (t) = A cos (ωt + φ).
Given that at t = 0, the initial velocity of the body is ω cm/s and its initial position is 1 cm, calculate its initial phase angle and amplitude?
If in place of the cosine function, a sine function is used to represent the simple harmonic motion:
x = B sin (ωt + α),
calculate the body’s amplitude and initial phase considering the initial conditions given above. [Angular frequency of the particle is π/ s]
Read each statement below carefully and state with reasons and examples, if it is true or false; A particle in one-dimensional motion
(a) with zero speed at an instant may have non-zero acceleration at that instant
(b) with zero speed may have non-zero velocity,
(c) with constant speed must have zero acceleration,
(d) with positive value of acceleration mustbe speeding up.
You have learnt that a travelling wave in one dimension is represented by a function y = f (x, t) where x and t must appear in the combination x - v t or x + v t, i.e. y = f (x ± v t). Is the converse true? Examine if the following functions for y can possibly represent a travelling wave:
(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)