Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
An aircraft executes a horizontal loop of radius 1.00 km with a steady speed of 900 km/h. Compare its centripetal acceleration with the acceleration due to gravity.
A bolt of mass 0.3 kg falls from the ceiling of an elevator moving down with an uniform speed of 7 m s-1. It hits the floor of the elevator (length of the elevator = 3 m) and does not rebound. What is the heat produced by the impact? Would your answer be different if the elevator were stationary?
A constant retarding force of 50 N is applied to a body of mass 20 kg moving initially with a speed of 15 ms–1. How long does the body take to stop?
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
Read each statement below carefully, and state, with reasons, if it is true or false;
(a) During rolling, the force of friction acts in the same direction as the direction of motion of the CM of the body.
(b) The instantaneous speed of the point of contact during rolling is zero.
(c) The instantaneous acceleration of the point of contact during rolling is zero.
(d) For perfect rolling motion, work done against friction is zero.
(e) A wheel moving down a perfectly frictionless inclined plane will undergo slipping (not rolling) motion.
A constant force acting on a body of mass 3.0 kg changes its speed from 2.0 m s–1 to 3.5 m s–1 in 25 s. The direction of the motion of the body remains unchanged. What is the magnitude and direction of the force?
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
During blood transfusion the needle is inserted in a vein where the gauge pressure is 2000 Pa. At what height must the blood container be placed so that blood may just enter the vein? [Use the density of whole blood from Table 10.1].
Which of the following examples represent (nearly) simple harmonic motion and which represent periodic but not simple harmonic motion?
(a) the rotation of earth about its axis.
(b) motion of an oscillating mercury column in a U-tube.
(c) motion of a ball bearing inside a smooth curved bowl, when released from a point slightly above the lower most point.
(d) general vibrations of a polyatomic molecule about its equilibrium position.