Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Textbooks on science may give you a wrong impression that studying science is dry and all too serious and that scientists are absent-minded introverts who never laugh or grin. This image of science and scientists is patently false. Scientists, like any other group of humans, have their share of humorists, and many have led their lives with a great sense of fun and adventure, even as they seriously pursued their scientific work. Two great physicists of this genre are Gamow and Feynman. You will enjoy reading their books listed in the Bibliography.
In deriving Bernoulli's equation, we equated the work done on the fluid in the tube to its change in the potential and kinetic energy. (a) What is the largest average velocity of blood flow in an artery of diameter 2 x 10-3 m if the flow must remain laminar? (b) Do the dissipative forces become more important as the fluid velocity increases? Discuss qualitatively.
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
In problem 10.9, if 15.0 cm of water and spirit each are further poured into the respective arms of the tube, what is the difference in the levels of mercury in the two arms? (Specific gravity of mercury = 13.6)
A body is initially at rest. It undergoes one-dimensional motion with constant acceleration. The power delivered to it at time t is proportional to
(i) t½ (ii) t (iii) t3/2 (iv) t2
Though the law gives women equal status in India, many people hold unscientific views on a woman’s innate nature, capacity and intelligence, and in practice give them a secondary status and role. Demolish this view using scientific arguments, and by quoting examples of great women in science and other spheres; and persuade yourself and others that, given equal opportunity, women are on par with men.
Figures 14.29 correspond to two circular motions. The radius of the circle, the period of revolution, the initial position, and the sense of revolution (i.e. clockwise or anti-clockwise) are indicated on each figure.
Obtain the corresponding simple harmonic motions of the x-projection of the radius vector of the revolving particle P, in each case.
A U-shaped wire is dipped in a soap solution, and removed. The thin soap film formed between the wire and the light slider supports a weight of 1.5 x 10-2 N (which includes the small weight of the slider). The length of the slider is 30 cm. What is the surface tension of the film?