Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Which of the following functions of time represent (a) simple harmonic, (b) periodic but not simple harmonic, and (c) non-periodic motion? Give period for each case of periodic motion (ω is any positive constant):
(a) sin ωt - cos wt
(b) sin3 ωt
(c) 3 cos (π/4 - 2ωt)
(d) cos ωt + cos 3ωt + cos 5ωt
(e) exp (-ω2t2)
Though India now has a large base in science and technology, which is fast expanding, it is still a long way from realising its potential of becoming a world leader in science. Name some important factors, which in your view have hindered the advancement of science in India.
Though the law gives women equal status in India, many people hold unscientific views on a woman’s innate nature, capacity and intelligence, and in practice give them a secondary status and role. Demolish this view using scientific arguments, and by quoting examples of great women in science and other spheres; and persuade yourself and others that, given equal opportunity, women are on par with men.
A family uses 8 kW of power. (a) Direct solar energy is incident on the horizontal surface at an average rate of 200 W per square meter. If 20% of this energy can be converted to useful electrical energy, how large an area is needed to supply 8 kW? (b) Compare this area to that of the roof of a typical house.
A string of mass 2.50 kg is under a tension of 200 N. The length of the stretched string is 20.0 m. If the transverse jerk is struck at one end of the string, how long does the disturbance take to reach the other end?
A travelling harmonic wave on a string is described by
y(x,t) = 7.5sin [0.0050x + 12t + π/4]
(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?
(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
A train, standing in a station-yard, blows a whistle of frequency 400 Hz in still air. The wind starts blowing in the direction from the yard to the station with at a speed of 10 m s-1. What are the frequency, wavelength, and speed of sound for an observer standing on the station's platform? Is the situation exactly identical to the case when the air is still and the observer runs towards the yard at a speed of 10 m s-1? The speed of sound in still air can be taken as 340 m s-1.