Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Two vessels have the same base area but different shapes. The first vessel takes twice the volume of water that the second vessel requires to fill upto a particular common height. Is the force exerted by the water on the base of the vessel the same in the two cases? If so, why do the vessels filled with water to that same height give different readings on a weighing scale?
Read the following two statements below carefully and state, with reasons, if it is true or false.
(a) The Young’s modulus of rubber is greater than that of steel;
(b) The stretching of a coil is determined by its shear modulus.
A bat is flitting about in a cave, navigating via ultrasonic beeps. Assume that the sound emission frequency of the bat is 40 kHz. During one fast swoop directly toward a flat wall surface, the bat is moving at 0.03 times the speed of sound in air. What frequency does the bat hear reflected off the wall?
For the wave described in Exercise 15.8, plot the displacement (y) versus (t) graphs for x = 0, 2 and 4 cm. What are the shapes of these graphs? In which aspects does the oscillatory motion in travelling wave differ from one point to another: amplitude, frequency or phase?
Three girls skating on a circular ice ground of radius 200 m start from a point P on the edge of the ground and reach a point Q diametrically opposite to P following different paths as shown in Fig. 4.20. What is the magnitude of the displacement vector for each? For which girl is this equal to the actual length of the path skated?
On a two-lane road, car A is travelling with a speed of 36 km h–1. Two cars B and C approach car A in opposite directions with a speed of 54 km h–1 each. At a certain instant, when the distance AB is equal to AC, both being 1 km, B decides to overtake A before C does. What minimum acceleration of car B is required to avoid an accident?
Does the escape speed of a body from the earth depend on
(a) the mass of the body,
(b) the location from where it is projected,
(c) the direction of projection,
(d) the height of the location from where the body is launched?
A block of mass 15 kg is placed on a long trolley. The coefficient of static friction between the block and the trolley is 0.18. The trolley accelerates from rest with 0.5 ms-2 for 20 s and then moves with uniform velocity. Discuss the motion of the block as viewed by (a) a stationary observer on the ground, (b) an observer moving with the trolley.
Ten one-rupee coins are put on top of each other on a table. Each coin has a mass m. Give the magnitude and direction of
(a) the force on the 7th coin (counted from the bottom) due to all the coins on its top,
(b) the force on the 7th coin by the eighth coin,
(c) the reaction of the 6th coin on the 7th coin.
A spring balance has a scale that reads from 0 to 50 kg. The length of the scale is 20 cm. A body suspended from this balance, when displaced and released, oscillates with a period of 0.6 s. What is the weight of the body?