Class 11 Chemistry - Chapter Thermodynamics NCERT Solutions | A reaction, A + B → C + D + q is fo

In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?

For the reaction, 2Cl_(g) → Cl_2(g),what are the signs of ΔH and ΔS ?

For the reaction at 298 K,

2A + B → C

ΔH = 400 kJ mol^-1and ΔS = 0.2 kJ K^-1mol^-1

At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?

The equilibrium constant for a reaction is 10. What will be the value of ΔG⁰ ?  R = 8.314 JK^–1 mol^–1, T = 300 K.

The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, –890.3 kJ mol^–1  , –393.5 kJ mol^–1, and –285.8 kJ mol^–1 respectively. Enthalpy of formation of CH₄(g) will be

(i) –74.8 kJ mol^–1

(ii) –52.27 kJ mol^–1

(iii) +74.8 kJ mol^–1

(iv) +52.26 kJ mol^–1

Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. Δ_fusH = 6.03 kJ mol^-1 at 0°C.

C_p[H₂O(l)] = 75.3 J mol^-1 K^-1

C_p[H₂O(s)] = 36.8 J mol^-1 K^-1

For an isolated system, ΔU = 0, what will be ΔS?

Calculate the enthalpy change for the process

CCl₄(g) → C(g) + 4 Cl(g)

and calculate bond enthalpy of C – Cl in CCl₄(g).

Δ_vapH⁰(CCl₄) = 30.5 kJ mol^–1.

Δ_fH⁰ (CCl₄) = –135.5 kJ mol^–1.

Δ_aH⁰ (C) = 715.0 kJ mol^–1 , where Δ_aH⁰ is enthalpy of atomisation

Δ_aH⁰ (Cl₂) = 242 kJ mol^–1

Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.

Enthalpies of formation of CO(g), CO₂(g), N₂O(g) and N₂O₄(g) are –110, – 393, 81 and 9.7 kJ mol–1 respectively. Find the value of Δ_rH for the reaction:

N₂O₄(g) + 3CO(g) → N₂O(g) + 3CO₂(g)

How do you account for the formation of ethane during chlorination of methane?

What are hybridisation states of each carbon atom in the following compounds ?

(i) CH₂=C=O,

(ii) CH₃CH=CH₂,

(iii) (CH₃)₂CO,

(iv) CH₂=CHCN,

(v) C₆H₆

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

What are the common physical and chemical features of alkali metals?

Calculate the molecular mass of the following:
(i) H₂O
(ii) CO₂
(iii) CH₄

Assign oxidation number to the underlined elements in each of the following species:

(a) NaH₂PO₄

(b) NaHSO₄

(c) H₄P₂O₇

(d) K₂MnO₄

(e) CaO₂

(f) NaBH₄

(g) H₂S₂O₇

(h) KAl(SO₄)₂.12 H₂O

What is the basic theme of organisation in the periodic table?

Explain the formation of a chemical bond.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.

Consider the reactions:

(a) H₃PO_2(aq) + 4 AgNO_3(aq) + 2 H₂O_(l) → H₃PO_4(aq) + 4Ag_(s) + 4HNO_3(aq)

(b) H₃PO_2(aq) + 2CuSO_4(aq) + 2 H₂O_(l) → H₃PO_4(aq) + 2Cu_(s) + H₂SO_4(aq)

(c) C₆H₅CHO_(l) + 2 [Ag (NH₃)₂]⁺_(aq) + 3OH^-_(aq) → C₆H₅COO^-_(aq) + 2Ag_(s) + 4NH_3(aq) + 2 H₂O_(l)

(d) C₆H₅CHO_(l) + 2Cu²⁺_(aq) + 5OH^-_(aq) → No change observed.

What inference do you draw about the behaviour of Ag⁺and Cu²⁺from these reactions?

Write the significance of a plus and a minus sign shown in representing the orbitals.

Lifetimes of the molecules in the excited states are often measured by using pulsed radiation source of duration nearly in the nano second range. If the radiation source has the duration of 2 ns and the number of photons emitted during the pulse source is 2.5 × 10¹⁵, calculate the energy of the source.

Write the expression for the equilibrium constant, K_c for each of the following reactions:

(i)   2NOCl (g)   ↔   2NO (g) + Cl₂ (g)

(ii)  2Cu(NO₃)₂ (s) ↔  2CuO (s) + 4NO₂ (g) + O₂ (g)

(iii) CH₃COOC₂H₅(aq) + H₂O(l) ↔  CH₃COOH (aq) + C₂H₅OH (aq)

(iv) Fe³⁺ (aq) + 3OH^– (aq) ↔  Fe(OH)₃ (s)

(v) I₂ (s) + 5F₂ ↔  2IF₅ 

Write the atomic number of the element present in the third period and seventeenth group of the periodic table.

How many electrons in an atom may have the following quantum numbers?

(a) n = 4,

(b) n = 3, l = 0

Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?

Give condensed and bond line structural formulas and identify the functional group(s) present, if any, for :

(a) 2,2,4-Trimethylpentane

(b) 2-Hydroxy-1,2,3-propanetricarboxylic acid

(c) Hexanedial

Chlorine is used to purify drinking water. Excess of chlorine is harmful. The excess of chlorine is removed by treating with sulphur dioxide. Present a balanced equation for this redox change taking place in water.

Pay load is defined as the difference between the mass of displaced air and the mass of the balloon. Calculate the pay load when a balloon of radius 10 m, mass 100 kg is filled with helium at 1.66 bar at 27°C. (Density of air = 1.2 kg m^–3 and R = 0.083 bar dm³ K^–1 mol^–1).