How is SO2 an air pollutant?
Sulphur dioxide causes harm to the environment in many ways:
1. It combines with water vapour present in the atmosphere to form sulphuric acid. This causes acid rain. Acid rain damages soil, plants, and buildings, especially those made of marble.
2. Even in very low concentrations, SO2 causes irritation in the respiratory tract. It causes throat and eye irritation and can also affect the larynx to cause breathlessness.
3. It is extremely harmful to plants. Plants exposed to sulphur dioxide for a long time lose colour from their leaves. This condition is known as chlorosis. This happens because the formation of chlorophyll is affected by the presence of sulphur dioxide.
Why is helium used in diving apparatus?
Why are pentahalides more covalent than trihalides?
Give the formula and describe the structure of a noble gas species which is isostructural with:
(i) ICl-4
(ii) IBr-2
(iii) BrO-3
Why is H2O a liquid and H2S a gas?
How is O3 estimated quantitatively?
What happens when sulphur dioxide is passed through an aqueous solution of Fe(III) salt?
Why is BiH3 the strongest reducing agent amongst all the hydrides of Group 15 elements?
Why are halogens strong oxidising agents?
Arrange the following in the order of property indicated for each set:
(i) F2, Cl2, Br2, I2- increasing bond dissociation enthalpy.
(ii) HF, HCl, HBr, HI - increasing acid strength.
(iii) NH3, PH3, AsH3, SbH3, BiH3- increasing base strength.
Comment on the nature of two S-O bonds formed in SO2 molecule. Are the two S-O bonds in this molecule equal?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
A first order reaction has a rate constant 1.15 10-3s-1. How long will 5 g of this reactant take to reduce to 3 g?
FeSO4 solution mixed with (NH4)2SO4 solution in 1:1 molar ratio gives the test of Fe2+ ion but CuSO4 solution mixed with aqueous ammonia in 1:4 molar ratio does not give the test of Cu2+ ion. Explain why?
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.
Define the term solution. How many types of solutions are formed? Write briefly about each type with an example.
The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
What is meant by hydroboration-oxidation reaction? Illustrate it with an example.
Where does the water present in the egg go after boiling the egg?
Explain the difference between Buna-N and Buna-S.
Explain the following terms with suitable examples
(i) cationic detergents
(ii) anionic detergents and
(iii) non-ionic detergents.