Why are powdered substances more effective adsorbents than their crystalline forms?
Adsorption is a surface phenomenon.The extent of adsorption depends on the surface area. Therefore, adsorption is directly proportional to the surface area.Increase in the surface area of the adsorbent, increases the total amount of gas adsorbed. A finely divided substance like nickel, platinum & porous substances like charcoal, silica gel provides large surface area but crystalline substances has less surface as compared to finely divided substances, as a result powered substances are more effective adsorbents than their crystalline forms.
Explain what is observed
(i) When a beam of light is passed through a colloidal sol.
(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.
(iii) Electric current is passed through a colloidal sol?
Why is adsorption always exothermic?
What do you mean by activity and selectivity of catalysts?
What modification can you suggest in the Hardy-Schulze law?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Why does physisorption decrease with the increase of temperature
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during recharging.
Write the conditions to maximize the yield of H2SO4 by Contact process.
Why are halogens coloured?
Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.
What happens when H3PO3 is heated?
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
A group 14 element is to be converted into n-type semiconductor by doping it with a suitable impurity. To which group should this impurity belong?
Give two examples to show the anomalous behaviour of fluorine.
Why do noble gases have comparatively large atomic sizes?
Explain
(i) The basis of similarities and differences between metallic and ionic crystals.
(ii) Ionic solids are hard and brittle.
Tqq soo much.. This is very helpful
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