Describe some features of catalysis by zeolites.
Zeolites are alumino-silicates that are micro-porous in nature. Zeolites have a honeycomb-like structure, which makes them shape-selective catalysts. They have an extended 3D-network of silicates in which some silicon atoms are replaced by aluminium atoms giving Al-O-Si framework. The reactions taking place in zeolites are very sensitive to the pores and cavity size of the zeolites. Zeolites are commonly used in the petrochemical industry.
Explain what is observed
(i) When a beam of light is passed through a colloidal sol.
(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.
(iii) Electric current is passed through a colloidal sol?
Why is adsorption always exothermic?
What do you mean by activity and selectivity of catalysts?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What modification can you suggest in the Hardy-Schulze law?
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Why does physisorption decrease with the increase of temperature
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Write structures of the compounds whose IUPAC names are as follows:
(i) 2-Methylbutan-2-ol
(ii) 1-Phenylpropan-2-ol
(iii) 3,5-Dimethylhexane -1, 3, 5-triol
(iv) 2,3 - Diethylphenol
(v) 1 - Ethoxypropane
(vi) 2-Ethoxy-3-methylpentane
(vii) Cyclohexylmethanol
(viii) 3-Cyclohexylpentan-3-ol
(ix) Cyclopent-3-en-1-ol
(x) 3-Chloromethylpentan-1-ol.
What is meant by unidentate, didentate and ambidentate ligands? Give two examples for each.
What inspired N. Bartlett for carrying out reaction between Xe and PtF6?
Discuss the main purpose of vulcanisation of rubber.
Give IUPAC names of the following ethers:
Write two main functions of carbohydrates in plants.
Discuss the trends in chemical reactivity of group 15 elements.
Name the macromolecules that are chosen as drug targets.
Explain why Cu+ ion is not stable in aqueous solutions?
How is leaching carried out in case of low grade copper ores?
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