What are emulsions? What are their different types? Give example of each type.
The colloidal solution in which both the dispersed phase and dispersion medium are liquids is called an emulsion.
There are two types of emulsions:
(a) Oil in water type:
Here, oil is the dispersed phase while water is the dispersion medium. For example: milk, vanishing cream, etc.
(b) Water in oil type:
Here, water is the dispersed phase while oil is the dispersion medium. For example: cold cream, butter, etc.
Explain what is observed
(i) When a beam of light is passed through a colloidal sol.
(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.
(iii) Electric current is passed through a colloidal sol?
Why is adsorption always exothermic?
What do you mean by activity and selectivity of catalysts?
What modification can you suggest in the Hardy-Schulze law?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Why does physisorption decrease with the increase of temperature
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
A group 14 element is to be converted into n-type semiconductor by doping it with a suitable impurity. To which group should this impurity belong?
Give two examples to show the anomalous behaviour of fluorine.
Why do noble gases have comparatively large atomic sizes?
Explain
(i) The basis of similarities and differences between metallic and ionic crystals.
(ii) Ionic solids are hard and brittle.
Explain the following with an example.
(i) Kolbe's reaction.
(ii) Reimer-Tiemann reaction.
(iii) Williamson ether synthesis.
(iv) Unsymmetrical ether.
Calculate the emf of the cell in which the following reaction takes place:
Ni(s) + 2Ag+ (0.002 M) → Ni2+ (0.160 M) + 2Ag(s)
Given that Eøcell = 1.05 V
A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):
(i) express this in percent by mass
(ii) determine the molality of chloroform in the water sample.
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Which aerosols deplete ozone?
Name the parameters that characterize a unit cell.
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