Explain what is observed
(i) When a beam of light is passed through a colloidal sol.
(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.
(iii) Electric current is passed through a colloidal sol?
(i) When a beam of light is passed through a colloidal solution, then scattering of light is observed. This is known as the Tyndall effect. This scattering of light illuminates the path of the beam in the colloidal solution.
(ii) When NaCl is added to ferric oxide sol, it dissociates to give Na+ and Cl- ions. Particles of ferric oxide sol are positively charged. Thus, they get coagulated in the presence of negatively charged Cl- ions.
(iii) The colloidal particles are charged and carry either a positive or negative charge. The dispersion medium carries an equal and opposite charge. This makes the whole system neutral. Under the influence of an electric current, the colloidal particles move towards the oppositely charged electrode. When they come in contact with the electrode, they lose their charge and coagulate.
Why is adsorption always exothermic?
What do you mean by activity and selectivity of catalysts?
What modification can you suggest in the Hardy-Schulze law?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Why does physisorption decrease with the increase of temperature
What are the factors which influence the adsorption of a gas on a solid?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
In the button cells widely used in watches and other devices the following reaction takes place:
Zn(s) + Ag2O(s) + H2O(l) → Zn2+(aq) + 2Ag(s) + 2OH - (aq)
Determine and for the reaction.
Arrange the following in increasing order of their basic strength:
(i) C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
(ii) C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2
(iii) CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2.
Why is H2O a liquid and H2S a gas?
Give plausible explanation for each of the following:
(i) Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
(ii) There are two -NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
(iii) During the preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, the water or the ester should be removed as soon as it is formed.
Why has it been difficult to study the chemistry of radon?
The decomposition of NH3on platinum surface is zero order reaction. What are the rates of production of N2and H2if k = 2.5 x 10-4mol-1L s-1?
In what way is the electronic configuration of the transition elements different from that of the non-transition elements?
What is glycogen? How is it different from starch?
Write the names of reagents and equations for the preparation of the following ethers by Williamson's synthesis:
(i) 1-Propoxypropane
(ii) Ethoxybenzene
(iii) 2-Methoxy-2-methylpropane
(iv) 1-Methoxyethane
Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.
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