What do you understand by activation of adsorbent? How is it achieved?
By activating an adsorbent, we tend to increase the adsorbing power of the adsorbent. Some ways to activate an adsorbent are:
(i) By increasing the surface area of the adsorbent. This can be done by breaking it into smaller pieces or powdering it.
(ii) Some specific treatments can also lead to the activation of the adsorbent. For example, wood charcoal is activated by heating it between 650 K and 1330 K in vacuum or air. It expels all the gases absorbed or adsorbed, thus creates a space for adsorption of gases.
Explain what is observed
(i) When a beam of light is passed through a colloidal sol.
(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.
(iii) Electric current is passed through a colloidal sol?
Why is adsorption always exothermic?
What do you mean by activity and selectivity of catalysts?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What modification can you suggest in the Hardy-Schulze law?
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Why does physisorption decrease with the increase of temperature
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
The decomposition of NH3on platinum surface is zero order reaction. What are the rates of production of N2and H2if k = 2.5 x 10-4mol-1L s-1?
What problem arises in using alitame as artificial sweetener?
Why does NH3 form hydrogen bond but PH3 does not?
What happens when PCl5 is heated?
What is the effect of denaturation on the structure of proteins?
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
Why is dioxygen a gas but sulphur a solid?
In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below:
A/ mol L - 1 |
0.20 | 0.20 | 0.40 |
B/ mol L - 1 |
0.30 | 0.10 | 0.05 |
r0/ mol L - 1 s - 1 |
5.07 × 10 - 5 |
5.07 × 10 - 5 |
1.43 × 10 - 4 |
What is the order of the reaction with respect to A and B?
Arrange the following compounds in increasing order of their boiling points.
CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3