(i) Calculate the total number of electrons present in one mole of methane.
(ii) Find
(a) the total number and
(b) the total mass of neutrons in 7 mg of 14C. (Assume that mass of a neutron = 1.675 × 10–27 kg).
(iii) Find
(a) the total number and
(b) the total mass of protons in 34 mg of NH3 at STP.
Will the answer change if the temperature and pressure are chang
(i) Molecule of CH4 (methane) contains electron = 10
Therefore 1 mole (6.022 x 1023 atoms) contains electron = 6.022 x 1024
(ii) a) 1g atom of 14C = 14g = 6.022 x 1023 atoms = 6.022 x 1024 x 8 neutrons
Thus 14g or 14000 mg have 6.022 x 1024 x 8 neutrons
Therefore 7 mg will have neutrons = 6.022 x 1024 x 8 / 14000 x 7 = 2.4088 x 1022
b) mass of 1 neutron = 1.675 x 10-27 kg
Therefore mass of 2.4088 x 1021 neutrons = 2.4088 x 1021 x 1.67 x 10-27 = 4.0347 x 10-6 kg
(iii) a) 1 mol of NH3 = 17g NH3 = 6.022 x 1023 molecules of NH3 = (6.022x1023)(7 + 3) proton = 6.022 x 1024 protons
Therefore 34 mg i.e 0.034 g NH3 = 6.022 x 1024 x 0.034/1 = 1.2044 x 1022 protons
b) mass of 1 proton = 1.6726 x 10-27 kg
Therefore mass of 1.2044 x 1022 protons = (1.6726 x 10-27)(1.2044 x 1022) kg = 2.0145 x 10-5 kg
No, the answer will not change with change in temperature & pressure.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Consider the elements:
Cs, Ne, I and F
(a) Identify the element that exhibits only negative oxidation state.
(b) Identify the element that exhibits only postive oxidation state.
(c) Identify the element that exhibits both positive and negative oxidation states.
(d) Identify the element which exhibits neither the negative nor does the positive oxidation state.
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
What are electrophiles and nucleophiles? Explain with examples.
A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The ammonia evolved was absorbed in 50 mL of 0.5 M H2SO4. The residual acid required 60 mL of 0.5 M solution of NaOH for neutralisation. Find the percentage composition of nitrogen in the compound.
Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040 (assume the density of water to be one).
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
Explain why alkyl groups act as electron donors when attached to a π system.
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
How much copper can be obtained from 100 g of copper sulphate (CuSO4)?
How many significant figures are present in the following?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126,000
(v) 500.0
(vi) 2.0034
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