How many neutrons and protons are there in the following nuclei?
We know atomic number(z) = no of protons = no of electrons
Also mass number(A) = no of protons + no of neutrons
136C:
Here mass number = 13
Atomic number = Number of protons = 6
Number of neutrons = (mass number) – (Atomic number)
= 13 – 6 = 7
:
Here mass number = 16
Atomic number = 8 Number of protons = 8 Number of neutrons = (mass number) – (Atomic number)
= 16 – 8 = 8
:
Here Mass number = 24
Atomic number = Number of protons = 12
Number of neutrons = (mass number) – (Atomic number)
= 24 – 12 = 12
:
Here mass number = 56
Atomic number = Number of protons = 26
Number of neutrons = (mass number ) – (Atomic number)
= 56 – 26 = 30
:
Here mass number = 88
Atomic number = Number of protons = 38
Number of neutrons = (mass number) – (Atomic number)
= 88 – 38 = 50
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
State as to why
(a) a solution of Na2CO3 is alkaline ?
(b) alkali metals are prepared by electrolysis of their fused chlorides ?
(c) sodium is found to be more useful than potassium ?
Consider the compounds, BCl3 and CCl4. How will they behave with water? Justify.
Explain structures of diborane and boric acid.
How can you explain higher stability of BCl3 as compared to TlCl3?
If ten volumes of dihydrogen gas react with five volumes of dioxygen gas, how many volumes of water vapour would be produced?
Define octet rule. Write its significance and limitations.
Pressure of 1 g of an ideal gas A at 27 °C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at same temperature the pressure becomes 3 bar. Find a relationship between their molecular masses.
Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
At 473 K, equilibrium constant Kc for decomposition of phosphorus pentachloride, PCl5 is 8.3 ×10-3. If decomposition is depicted as,
PCl5 (g) ↔ PCl3 (g) + Cl2 (g) ΔrH0 = 124.0 kJ mol–1
(a) write an expression for Kc for the reaction.
(b) what is the value of Kc for the reverse reaction at the same temperature ?
(c) what would be the effect on Kc if (i) more PCl5 is added (ii) pressure is increased (iii) the temperature is increased ?
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