Critical temperature for carbon dioxide and methane are 31.1 °C and –81.9 °C respectively. Which of these has stronger intermolecular forces and why?
The maximum temperature at which a gas can be converted into a liquid by an increase in pressure is called its critical temperature(Tc). This means that the intermolecular forces of attraction between the molecules of a gas are directly proportional to its critical temperature. Hence, intermolecular forces of attraction are stronger in the case of CO2.
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bar.
(R = 0.083 bar dm3 K–1 mol–1).
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
What would be the SI unit for the quantity pV2T 2/n?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Write reactions to justify amphoteric nature of aluminium.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
(a) Classify following oxides as neutral, acidic, basic or amphoteric:
CO, B2O3, SiO2, CO2, Al2O3, PbO2, Tl2O3
(b) Write suitable chemical equations to show their nature.
Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.
What is the state of hybridisation of carbon in
(a) CO2-3
(b) diamond
(c) graphite?
Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol-1. Calculate the heat released upon formation of 35.2 g of CO2 from carbon and dioxygen gas.
Does the number of moles of reaction products increase, decrease or remain same when each of the following equilibria is subjected to a decrease in pressure by increasing the volume?
(a) PCl5 (g) ↔ PCl3 (g) + Cl2 (g)
(b) CaO (s) + CO2 (g) ↔ CaCO3 (s)
(c) 3Fe (s) + 4H2O (g) ↔ Fe3O4 (s) + 4H2 (g)
What do you understand by (i) electron-deficient, (ii) electron-precise, and (iii) electron-rich compounds of hydrogen? Provide justification with suitable examples.
A certain particle carries 2.5 × 10–16C of static electric charge. Calculate the number of electrons present in it.
Intermolecular forces of methane is more than of carbon dioxide
But the critical temperature of methane is more as compared to carbon dioxide
Thanks
It was very good...small but explainable