What will be the pressure of the gaseous mixture when 0.5 L of H2 at 0.8 bar and 2.0 L of dioxygen at 0.7 bar are introduced in a 1L vessel at 27°C?
From the equation Pv = n RT for the two gases. We can write
0.8 x 0.5 = nH2 x RT or nH2 = 0.8 x 0.5 / RT
ALSO 0.7 x 2.0 = n02 . RT or n02 = 0.7 x 2 / RT
When introduced in 1 L vessel, then
Px1L = (n02 + nH2) RT
Putting the values, we get
P = 0.4 + 1.4 = 1.8 bar
Hence, the total pressure of the gaseous mixture in the vessel is 1.8 bar
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bar.
(R = 0.083 bar dm3 K–1 mol–1).
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
What would be the SI unit for the quantity pV2T 2/n?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
How does H2O2 behave as a bleaching agent?
(a) How many sub-shells are associated with n = 4?
(b) How many electrons will be present in the sub-shells having ms value of –1/2 for n = 4?
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Is boric acid a protic acid? Explain.
The ionization constant of dimethylamine is 5.4 x 10-4. Calculate its degree of ionization in its 0.02 M solution. What percentage of dimethylamine is ionized if the solution is also 0.1 M in NaOH?
If 0.561 g of KOH is dissolved in water to give 200 mL of solution at 298 K. Calculate the concentrations of potassium, hydrogen and hydroxyl ions. What is its pH?
Why does the following reaction occur ?
XeO4– 6(aq) + 2F – (aq) + 6H + (aq) → XeO3(g) + F2(g) + 3H2O(l)
What conclusion about the compound Na4XeO6 (of which XeO4– 6 is a part) can be drawn from the reaction.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol–1
Explain structures of diborane and boric acid.
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