Class 11 Chemistry - Chapter States of Matter NCERT Solutions | Using the equation of state pV = nRT; sh

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

Calculate the temperature of 4.0 mol of a gas occupying 5 dm³ at 3.32 bar.

(R = 0.083 bar dm³ K^–1 mol^–1).

A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?

Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm³ at 27°C. R = 0.083 bar dm³ K^–1 mol^–1.

Calculate the volume occupied by 8.8 g of CO₂ at 31.1°C and 1 bar pressure.

R = 0.083 bar L K^–1 mol^–1.

34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?

2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?

What would be the SI unit for the quantity pV²T ²/n?

How do you account for the formation of ethane during chlorination of methane?

What are hybridisation states of each carbon atom in the following compounds ?

(i) CH₂=C=O,

(ii) CH₃CH=CH₂,

(iii) (CH₃)₂CO,

(iv) CH₂=CHCN,

(v) C₆H₆

What are the common physical and chemical features of alkali metals?

Calculate the molecular mass of the following:
(i) H₂O
(ii) CO₂
(iii) CH₄

Assign oxidation number to the underlined elements in each of the following species:

(a) NaH₂PO₄

(b) NaHSO₄

(c) H₄P₂O₇

(d) K₂MnO₄

(e) CaO₂

(f) NaBH₄

(g) H₂S₂O₇

(h) KAl(SO₄)₂.12 H₂O

What is the basic theme of organisation in the periodic table?

Explain the formation of a chemical bond.

Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.

One mole of H₂O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium 40% of water (by mass) reacts with CO according to the equation,

H₂O (g) + CO (g) ↔  H₂ (g) + CO₂ (g)

Calculate the equilibrium constant for the reaction.

What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to n = 2 of He⁺ spectrum?

Calculate a) ΔG0 and b) the equilibrium constant for the formation of NO₂ from NO and O₂ at 298K

NO (g) + ½ O₂ (g) ↔ NO₂ (g)

where Δ_fG⁰ (NO₂) = 52.0 kJ/mol

Δ_fG⁰ (NO) = 87.0 kJ/mol

Δ_fG⁰ (O₂) = 0 kJ/mol

How would you convert the following compounds into benzene?

(i) Ethyne         (ii) Ethene          (iii) Hexane

Similar to electron diffraction, neutron diffraction microscope is also used for the determination of the structure of molecules. If the wavelength used here is 800 pm, calculate the characteristic velocity associated with the neutron.

Calculate the pH of the following solutions:

(a) 2 g of TlOH dissolved in water to give 2 litre of solution.

(b) 0.3 g of Ca(OH)₂ dissolved in water to give 500 mL of solution.

(c) 0.3 g of NaOH dissolved in water to give 200 mL of solution.

(d) 1mL of 13.6 M HCl is diluted with water to give 1 litre of solution.

What is the difference between the terms 'hydrolysis' and 'hydration'?

The size of isoelectronic species — F^–, Ne and Na⁺ is affected by

(a) Nuclear charge (Z )

(b) Valence principal quantum number (n)

(c) Electron-electron interaction in the outer orbitals

(d) None of the factors because their size is the same.

For the reaction

2 A(g) + B(g) → 2D(g)

ΔU⁰ = –10.5 kJ and ΔS⁰ = –44.1 JK^–1.

Calculate ΔG⁰ for the reaction, and predict whether the reaction may occur spontaneously.

Use molecular orbital theory to explain why the Be2 molecule does not exist.