A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
According to Boyle’s Law P1 V1 = P2 V2
Here the temperature is constant. Therefore
1.2 X 120 = P2 X 180
OR
P2 = 1.2 X 120 /180 = 0.8 bar
Therefore, the pressure would be 0.8 bar.
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bar.
(R = 0.083 bar dm3 K–1 mol–1).
Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
What would be the SI unit for the quantity pV2T 2/n?
Pay load is defined as the difference between the mass of displaced air and the mass of the balloon. Calculate the pay load when a balloon of radius 10 m, mass 100 kg is filled with helium at 1.66 bar at 27°C. (Density of air = 1.2 kg m–3 and R = 0.083 bar dm3 K–1 mol–1).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Fluorine reacts with ice and results in the change:
H2O(s) + F2(g) → HF(g) + HOF(g)
Justify that this reaction is a redox reaction.
The ionization constant of HF, HCOOH and HCN at 298K are 6.8 × 10–4, 1.8 × 10–4 and 4.8 × 10–9 respectively.
Calculate the ionization constants of the corresponding conjugate base.
An ion with mass number 37 possesses one unit of negative charge. If the ion contains 11.1% more neutrons than the electrons, find the symbol of the ion.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
What properties of water make it useful as a solvent? What types of compound can it (i) dissolve, and (ii) hydrolyse?
Explain why the following systems are not aromatic?
What are the major differences between metals and non-metals?
For the reaction at 298 K,
2A + B → C
ΔH = 400 kJ mol-1and ΔS = 0.2 kJ K-1mol-1
At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?
Predict the products of electrolysis in each of the following:
(i) An aqueous solution of AgNO3 with silver electrodes
(ii) An aqueous solution AgNO3 with platinum electrodes
(iii) A dilute solution of H2SO4 with platinum electrodes
(iv) An aqueous solution of CuCl2 with platinum electrodes.
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