Convert the following into basic units:
(i) 28.7 pm
(ii) 15.15 pm
(iii) 25365 mg
(i) 28.7 pm:
1 pm = 10–12 m
28.7 pm = 28.7 × 10–12 m
= 2.87 × 10–11 m
(ii) 15.15 pm:
1 pm = 10–12 m
15.15 pm = 15.15 × 10–12 m
= 1.515 × 10–12 m
(iii) 25365 mg:
1 mg = 0.01 kg
Therefore 25365 mg = 0.01/1 x 25365= 253.65 kg
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous hydrochloric acid according to the reaction
4HCl(aq) + MnO2(s) → 2H2O(l) + MnCl2(aq) + Cl2(g)
How many grams of HCl react with 5.0 g of manganese dioxide?
Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% dioxygen by mass.
A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction,
CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?
Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol–1
A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate
(i) empirical formula,
(ii) molar mass of the gas, and
(iii) molecular formula.
How many significant figures are present in the following?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126,000
(v) 500.0
(vi) 2.0034
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place, further show:
(i) which of the electrode is negatively charged,
(ii) the carriers of the current in the cell, and
(iii) individual reaction at each electrode.
The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, –890.3 kJ mol–1 , –393.5 kJ mol–1, and –285.8 kJ mol–1 respectively. Enthalpy of formation of CH4(g) will be
(i) –74.8 kJ mol–1
(ii) –52.27 kJ mol–1
(iii) +74.8 kJ mol–1
(iv) +52.26 kJ mol–1
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Which one of the following statements is incorrect in relation to ionization enthalpy?
(a) Ionization enthalpy increases for each successive electron.
(b) The greatest increase in ionization enthalpy is experienced on removal of electron from core noble gas configuration.
(c) End of valence electrons is marked by a big jump in ionization enthalpy.
(d) Removal of electron from orbitals bearing lower n value is easier than from orbital having higher n value.
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
What effect does branching of an alkane chain has on its boiling point?
Explain what happens when boric acid is heated.
Explain, why an organic liquid vaporises at a temperature below its boiling point in its steam distillation?
Explain why is sodium less reactive than potassium?
How would you explain the lower atomic radius of Ga as compared to Al?
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Second and is 10^-11