State Henry's law and mention some important applications?
Henry’s law states that the mass of a gas dissolved per unit volume of the solvent at a given temperature is proportional to the pressure of the gas in equilibrium with the solution.
Or
It also states that the pressure of a gas over a solution in which the gas is dissolved is proportional to the mole fraction of the gas dissolved in the solution.
The important applications of Henry’s law are as follows:
1) In the production of carbonated beverages-in order to increase the solubility of CO2 in cold drinks,beer etc., the bottle are sealed under high pressure. When the bottle is opened under normal atmospheric pressure, the pressure inside the bottle falls to atmospheric pressure & the excess CO2 bubbles out of the bottle causing effervescence.
2) At high altitudes-the partial pressure of oxygen at high altitudes is less than the ground level. This results in low concentration of oxygen in the blood & tissues of the peoples.
3) In scuba diving- during scuba diving,when the diver breaths in compressed air from the supply tank, more nitrogen dissolves in the blood & other body fluids because the pressure at that depth is far greater than the surface atmospheric pressure.
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
H2S, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H2S in water at STP is 0.195 m, calculate Henry's law constant.
An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?
Boiling point of water at 750 mm Hg is 99.63°C. How much sucrose is to be added to 500 g of water such that it boils at 100°C.Molal elevation constant for water is 0.52 K kg mol-1.
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
What is the effect of denaturation on the structure of proteins?
What is meant by unidentate, didentate and ambidentate ligands? Give two examples for each.
Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
What is shape selective catalysis?
Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O.
How much charge is required for the following reductions:
(i) 1 mol of Al3+ to Al.
(ii) 1 mol of Cu2+ to Cu.
(iii) 1 mol of MnO4- to Mn2+.
Show how are the following alcohols prepared by the reaction of a suitable
Grignard reagent on methanal?
(i)
(ii)
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
The rate constant for the first order decomposition of H2O2 is given by the following equation:
log k = 14.34 - 1.25 x 104 K/T
Calculate Ea for this reaction and at what temperature will its half-period be 256 minutes?
A group 14 element is to be converted into n-type semiconductor by doping it with a suitable impurity. To which group should this impurity belong?
OK sir
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Thanks a lot
Mst and easily explained
Tq ...easy explanation
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So helpful
Sir what will be the effect on solubility if we increase in temperature.
Easy to study