How is dacron obtained from ethylene glycol and terephthalic acid?
Dacron (terylene) is obtained by the polymerization of ethylene glycol and terephthalic acid at 420 to 460 K in the presence of zinc acetate-antimony trioxide catalyst.
The reaction is as follows:
It is used in blending with cotton or wool fibres, as glass reinforcing materials in safety helmets, for making magnetic recording tapes.
Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
How are polymers classified on the basis of structure?
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Explain the following with suitable examples:
(i) Ferromagnetism
(ii)Paramagnetism
(iii)Ferrimagnetism
(iv)Antiferromagnetism
(v)12-16 and 13-15 group compounds.
What is spectrochemical series? Explain the difference between a weak field ligand and a strong field ligand.
Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water. Ka = 1.4 x 10-3, Kf = 1.86 K kg mol-1.
The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
A group 14 element is to be converted into n-type semiconductor by doping it with a suitable impurity. To which group should this impurity belong?
The rate constant for the decomposition of hydrocarbons is 2.418 x 10-5 s-1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor.
Ionic solids conduct electricity in molten state but not in solid state. Explain.
Define the following terms:
(i) Mole fraction (ii) Molality (iii) Molarity (iv) Mass percentage.
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.
Name the macromolecules that are chosen as drug targets.
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