Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
Polymer |
Monomer |
Structure of monomer |
|
i |
Buna-S |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Styrene |
C6H5CH = CH2 |
||
ii |
Buna-N |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Acrylonitrile |
CH2 = CH – CN |
||
iii |
Neoprene |
Chloroprene |
|
iv |
Dacron |
Ethylene glycol |
HOH2C –CH2OH |
Terephthalic acid |
|
1) Buna-S (styrene butadiene rubber) - It is obtained by the polymerization of Buta-1, 3 -diene and styrene in the ratio of 3:1 in the presence of sodium. It is used for making automobile tyres and footwear.
2) Buna-N (Nitrile rubber)- It is obtained by polymerization of 1,3-butadiene and acrylonitrile in the presence of a peroxide catalyst. It is used for making oil seals, manufacture of hoses and tank linings.
3) Dacron – It is obtained by the polymerization of ethylene glycol and terphthalic acid.
4) Neoprene –It is prepared by the free radical polymerization of chloroprene. It is used as insulator, for making belts, gaskets, hoses etc.
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
How are polymers classified on the basis of structure?
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
What are the monomeric repeating units of Nylon-6 and Nylon-6, 6?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
What type of solids are electrical conductors, malleable and ductile?
Why is H2O a liquid and H2S a gas?
The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 Kif the Henry's law constants for oxygen and nitrogen are 3.30 x 107 mm and 6.51 x 107mm respectively, calculate the composition of these gases in water.
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
2.0 × 10 - 2 |
II | -- | 0.2 |
4.0 × 10 - 2 |
III | 0.4 | 0.4 | -- |
IV | -- | 0.2 |
2.0 × 10 - 2 |
What are monosaccharides?
100 g of liquid A (molar mass 140 g mol-1) was dissolved in 1000 g of liquid B (molar mass 180 g mol-1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 Torr.
Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rd of tetrahedral voids. What is the formula of the compound?
Compare the stability of +2 oxidation state for the elements of the first transition series.
Write IUPAC names of the following compounds:
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What are the monomer repeating units of nylon-6 and nylon-6,6
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proved beneficial to me.. thnx 4 giving glimpse of monomers of polymers....
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