What are the monomeric repeating units of Nylon-6 and Nylon-6, 6?
The monomeric repeating unit of nylon 6 is [NH – (CH2)5 – CO], which is derived from Caprolactam.
The monomeric repeating unit of nylon 6, 6 is [NH – (CH2)6 - NH – CO – (CH2)4 – CO], which is derived from hexamethylene diamine and adipic acid.
Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
How are polymers classified on the basis of structure?
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Predict the products of the following reactions:
(i)
(ii)
(iii)
(iv)
Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show cleavage property?
What are ambident nucleophiles? Explain with an example.
For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.
Show how are the following alcohols prepared by the reaction of a suitable
Grignard reagent on methanal?
(i)
(ii)
Which one of the following does not exist?
(i) XeOF4
(ii) NeF2
(iii) XeF2
(iv) XeF6
Write chemical reaction for the preparation of phenol from chlorobenzene.
Give the equations of reactions for the preparation of phenol from cumene.
What is the role of cryolite in the metallurgy of aluminium?
Write the electronic configurations of the elements with the atomic numbers 61, 91, 101, and 109.
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