Class 12 Chemistry - Chapter Polymers NCERT Solutions | Define the term polymerisation.

Write the names and structures of the monomers of the following polymers:

(i) Buna-S  (ii) Buna-N

(iii) Dacron  (iv) Neoprene

What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.

Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.

Explain the difference between Buna-N and Buna-S.

How are polymers classified on the basis of structure?

Define thermoplastics and thermosetting polymers with two examples of each.

Explain the term copolymerisation and give two examples.

Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite

How do you explain the functionality of a monomer?

Identify the monomer in the following polymeric structures.

(i)

(ii)

For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.

Write the formulas for the following coordination compounds:

(i) Tetraamminediaquacobalt (III) chloride

(ii) Potassium tetracyanonickelate(II)

(iii) Tris(ethane-1,2-diamine) chromium(III) chloride

(iv) Amminebromidochloridonitrito-N-platinate(II)

(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate

(vi) Iron(III) hexacyanoferrate(II)

(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N

(ii) Write IUPAC names of all the isomers.

(iii) What type of isomerism is exhibited by different pairs of amines?

Why are solids rigid?

Write any two characteristics of Chemisorption.

Write the structures of the following compounds.

(i) α-Methoxypropionaldehyde

(ii) 3-Hydroxybutanal

(iii) 2-Hydroxycyclopentane carbaldehyde

(iv) 4-Oxopentanal

(v) Di-sec-butyl ketone

(vi) 4-Fluoroacetophenone

Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?

Why are pentahalides more covalent than trihalides?

Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?

Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.

Explain how does the -OH group attached to a carbon of benzene ring activate it towards electrophilic substitution?

You are given benzene, conc. H₂SO₄ and NaOH. Write the equations for the preparation of phenol using these reagents.

The rate constant for the decomposition of N₂O₅ at various temperatures is given below:

Draw a graph between ln k and 1/T and calculate the values of A and E_a.

Predict the rate constant at 30 º and 50 ºC.

Explain:   (i) Zone refining    (ii) Column chromatography.

For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.

Calculate the rate constant

How can you separate alumina from silica in bauxite ore associated with silica? Give equations, if any.

Identify allylic alcohols in the above examples.

Write structures of the products of the following reactions:

(i)

(ii)

(iii)

The rate constant for the decomposition of hydrocarbons is 2.418 x 10^-5 s^-1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor.

From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.

(i) 3 NO(g) → N₂O(g)  Rate = k[NO]²

(ii) H₂O₂ (aq) + 3 I ^- (aq) + 2 H⁺→ 2 H₂O (l) +  I₃^-  Rate = k[H₂O₂][I ^- ]

(iii) CH₃CHO(g)  → CH₄(g) + CO(g)  Rate = k [CH₃CHO]^3/2

(iv) C₂H₅Cl(g) → C₂H₄(g) + HCl(g)  Rate = k [C₂H₅Cl]