Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
The process of treating permanent hardness of water using synthetic resins is based on the exchange of cations (e.g., Na+, Ca2+, Mg2+ etc) and anions (e.g., Cl-, SO2-4, HCO-3 etc) present in water by H+ and OH- ions respectively.
Synthetic resins are of two types:
1) Cation exchange resins
2) Anion exchange resins
Cation exchange resins are large organic molecules that contain the -SO3H group. The resin is firstly changed to RNa (from RSO3H) by treating it with NaCl. This resin then exchanges Na+ ions with Ca2+ and Mg2+ ions, thereby making the water soft.
2RNa + M2+ (aq) → R2M(s) + 2Na + (aq)
There are cation exchange resins in H+ form. The resins exchange H+ ions for Na+, Ca2+, and Mg2+ ions.
Anion exchange resins exchange OH- ions for anions like Cl-,HCO-3, and SO42- present in water.
During the complete process, water first passes through the cation exchange process. The water obtained after this process is free from mineral cations and is acidic in nature.
This acidic water is then passed through the anion exchange process where OH- ions neutralize the H+ ions and de-ionize the water obtained.
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the structures of H2O and H2O2.
Write chemical reactions to show the amphoteric nature of water.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
Arrange the following
(i) CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
(ii) LiH, NaH and CsH in order of increasing ionic character.
(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.
(iv) NaH, MgH2 and H2O in order of increasing reducing property.
What is meant by 'demineralised' water and how can it be obtained?
What causes the temporary and permanent hardness of water?
How does H2O2 behave as a bleaching agent?
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Critical temperature for carbon dioxide and methane are 31.1 °C and –81.9 °C respectively. Which of these has stronger intermolecular forces and why?
Write the expression for the equilibrium constant, Kc for each of the following reactions:
(i) 2NOCl (g) ↔ 2NO (g) + Cl2 (g)
(ii) 2Cu(NO3)2 (s) ↔ 2CuO (s) + 4NO2 (g) + O2 (g)
(iii) CH3COOC2H5(aq) + H2O(l) ↔ CH3COOH (aq) + C2H5OH (aq)
(iv) Fe3+ (aq) + 3OH– (aq) ↔ Fe(OH)3 (s)
(v) I2 (s) + 5F2 ↔ 2IF5
Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
What is the pH of 0.001 M aniline solution? The ionization constant of aniline can be taken from Table 7.7. Calculate the degree of ionization of aniline in the solution. Also calculate the ionization constant of the conjugate acid of aniline.
A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% dioxygen by mass.
What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to n = 2 of He+ spectrum?
Calculate the standard enthalpy of formation of CH3OH(l) from the following data:
CH3OH (l) + 3/2 O2(g) → CO2(g) + 2H2O(l) ; ΔrH0 = –726 kJ mol–1
C(g) + O2(g) → CO2(g) ; ΔcH0 = –393 kJ mol–1
H2(g) + 1/2 O2(g) → H2O(l) ; ΔfH0 = –286 kJ mol–1.
The equilibrium constant for a reaction is 10. What will be the value of ΔG0 ? R = 8.314 JK–1 mol–1, T = 300 K.
Calculate the number of atoms in each of the following
(i) 52 moles of Ar
(ii) 52 u of He
(iii) 52 g of He.