Class 11 Chemistry - Chapter Hydrogen NCERT Solutions | What do you understand by the term &ldqu

Welcome to the NCERT Solutions for Class 11th Chemistry - Chapter Hydrogen. This page offers a step-by-step solution to the specific question from Exercise 1, Question 11: what do you understand by the term ldquo non stoi....
Question 11

What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.

Answer

Non-Stoichiometric hydrides are hydrogen-deficient compounds formed by the reaction of dihydrogen with d-block and f-block elements. These hydrides do not follow the law of constant composition. For example: LaH2.87, YbH2.55, TiH1.5 - 1.8 etc.

Alkali metals form stoichiometric hydrides. These hydrides are ionic in nature. Hydride ions have comparable sizes (208 pm) with alkali metal ions. Hence, strong binding forces exist between the constituting metal and hydride ion. As a result, stoichiometric hydrides are formed.

Alkali metals will not form non-stoichiometric hydrides.

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