Class 11 Chemistry - Chapter Hydrogen NCERT Solutions | What characteristics do you expect from

Welcome to the NCERT Solutions for Class 11th Chemistry - Chapter Hydrogen. This page offers a step-by-step solution to the specific question from Exercise 1, Question 9: what characteristics do you expect from an electro....
Question 9

What characteristics do you expect from an electron-deficient hydride with respect to its structure and chemical reactions?

Answer

An electron-deficient hydride does not have sufficient electrons to form a regular bond in which two electrons are shared by two atoms e.g., B2H6, Al2H6 etc.

These hydrides cannot be represented by conventional Lewis structures. B2H6, for example, contains four regular bonds and two three centered-two electron bond. Its structure can be represented as:

Since these hydrides are electron-deficient, they have a tendency to accept electrons. Hence, they act as Lewis acids.

B2H  +  2NMe    →    2BH3 . NMe3

B2H  +  2CO    →    2BH3 . CO

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