What is meant by the term "chromatography"?
Chromatography is a collective term used for a family of laboratory techniques for the separation of mixtures. The term is derived from Greek words 'chroma' meaning 'colour' and 'graphein' meaning 'to write'. Chromatographic techniques are based on the principle that different components are absorbed differently on an absorbent. There are several chromatographic techniques such as paper chromatography, column chromatography, gas chromatography etc.
What is the significance of leaching in the extraction of aluminium?
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
Copper can be extracted by hydrometallurgy but not zinc. Explain.
Outline the principles of refining of metals by the following methods:
(i) Zone refining
(ii) Electrolytic refining
(iii) Vapour phase refining
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present ?
The reaction,
Cr2O3 + 2Al → Al2O3 + 2Cr (ΔGo = -421kJ)
is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?
How can you separate alumina from silica in bauxite ore associated with silica? Give equations, if any.
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Write chemical reactions taking place in the extraction of zinc from zinc blende.
Describe a method for refining nickel.
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Draw the structures of the following compounds.
(i) 3-Methylbutanal (ii) p-Nitropropiophenone
(iii) p-Methylbenzaldehyde (iv) 4-Methylpent-3-en-2-one
(v) 4-Chloropentan-2-one (vi) 3-Bromo-4-phenylpentanoic acid
(vii) p,p'-Dihydroxybenzophenone (viii) Hex-2-en-4-ynoic acid
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal' pchloroform' and pacetoneas a function of xacetone. The experimental data observed for different compositions of mixture is.
100 ×xacetone |
0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
pacetone /mm Hg |
0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
pchloroform/mm Hg |
632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
If the density of some lake water is 1.25 g mL-1 and contains 92 g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake.
Actinoid contraction is greater from element to element than lanthanoid contraction. Why?
How is dacron obtained from ethylene glycol and terephthalic acid?
Write the conditions to maximize the yield of H2SO4 by Contact process.
Bond angle in PH+4 is higher than that in PH3. Why?
Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
What are biodegradable and non-biodegradable detergents? Give one example of each.
Why are cimetidine and ranitidine better antacids than sodium hydrogencarbonate or magnesium or aluminium hydroxide ?