What is smog? How is classical smog different from photochemical smog?
Smog is a kind of air pollution. It is the combination of smoke and fog. There are two kinds of smog:
a) Classical smog
b) Photochemical smog
The two smog can be differentiated as follows:
Classical smog:
It occurs in a cool, humid climate.
Its components are smoke, fog, and Sulphur dioxide.
It is reducing in nature.
Photochemical smog:
It occurs in a dry, sunny climate.
Its components are PAN, acrolein, ozone, formaldehyde, and nitric oxide.
It is oxidizing in nature.
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
What are the harmful effects of photochemical smog and how can they be controlled?
Write down the reactions involved during the formation of photochemical smog.
Explain tropospheric pollution in 100 words.
What are the reactions involved for ozone layer depletion in the stratosphere?
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
Statues and monuments in India are affected by acid rain. How?
What do you mean by green chemistry? How will it help decrease environmental pollution?
What do you mean by ozone hole? What are its consequences?
A large number of fish are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish kill.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
For the process to occur under adiabatic conditions, the correct condition is:
(i) ΔT = 0
(ii) Δp = 0
(iii) q = 0
(iv) w = 0
Write chemical equations for combustion reaction of the following hydrocarbons:
(i) Butane
(ii) Pentene
(iii) Hexyne
(iv) Toluene
Write the resonance structures for SO3, NO2 and .
Suggest a list of the substances where carbon can exhibit oxidation states from -4 to +4 and nitrogen from -3 to +5.
At 700 K, equilibrium constant for the reaction:
H2 (g) + I2 (g) ↔ 2HI (g)
is 54.8. If 0.5 mol L–1 of HI(g) is present at equilibrium at 700 K, what are the concentration of H2(g) and I2(g) assuming that we initially started with HI(g) and allowed it to reach equilibrium at 700K?
If the starting material for the manufacture of silicones is RSiCl3, write the structure of the product formed.
What is the equilibrium concentration of each of the substances in the equilibrium when the initial concentration of ICl was 0.78 M ?
2ICl (g) ↔ I2 (g) + Cl2 (g); Kc = 0.14
What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp2, sp3 hybrid orbitals.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
The first (ΔiH1) and the second (ΔiH) ionization enthalpies (in kJ mol–1) and the (ΔegH) electron gain enthalpy (in kJ mol–1) of a few elements are given below:
Elements | ΔiH1 | ΔiH | ΔegH |
I | 520 | 7300 | -60 |
II | 419 | 3051 | -48 |
III | 1681 | 3374 | -328 |
IV | 1008 | 1846 | -295 |
V | 2372 | 5251 | +48 |
VI | 738 | 1451 | -40 |
Which of the above elements is likely to be :
(a) the least reactive element.
(b) the most reactive metal.
(c) the most reactive non-metal.
(d) the least reactive non-metal.
(e) the metal which can form a stable binary halide of the formula MX2, (X=halogen).
(f) the metal which can form a predominantly stable covalent halide of the formula MX (X=halogen)?
Satisfactory
Satisfactory answers