What do you mean by Biochemical Oxygen Demand (BOD)?
Biochemical oxygen demand is the amount of oxygen required by bacteria to decompose organic matter in a certain volume of sample of water. Clean water would have a BOD value of less than 5 ppm, whereas highly polluted water has a BOD value of more than or equal to 17 ppm.
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
What are the harmful effects of photochemical smog and how can they be controlled?
Write down the reactions involved during the formation of photochemical smog.
Explain tropospheric pollution in 100 words.
What are the reactions involved for ozone layer depletion in the stratosphere?
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
Statues and monuments in India are affected by acid rain. How?
What do you mean by green chemistry? How will it help decrease environmental pollution?
What is smog? How is classical smog different from photochemical smog?
What do you mean by ozone hole? What are its consequences?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Predict which of the following reaction will have appreciable concentration of reactants and products:
a) Cl2 (g) ↔ 2Cl (g) Kc = 5 ×10–39
b) Cl2 (g) + 2NO (g) ↔ 2NOCl (g) Kc = 3.7 × 108
c) Cl2 (g) + 2NO2 (g) ↔ 2NO2Cl (g) Kc = 1.8
The electron energy in hydrogen atom is given by En = (–2.18 × 10–18)/n2 J. Calculate the energy required to remove an electron completely from the n = 2 orbit. What is the longest wavelength of light in cm that can be used to cause this transition?
Elements of group 14
(a) exhibit oxidation state of +4 only
(b) exhibit oxidation state of +2 and +4
(c) form M2-and M4+ion
(d) form M2+and M4+ions
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
Write balanced equations for:
(i) BF3 + LiH →
(ii) B2H6 + H2O →
(iii) NaH + B2H6 →
(iv) H3BO3
(v) Al + NaOH →
(vi) B2H6 + NH3 →
ΔU0of combustion of methane is – X kJ mol–1. The value of ΔH0 is
(i) = ΔU0
(ii) > ΔU0
(iii) < ΔU0
(iv) = 0
Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) E° for M2+(aq) (where M = Ca, Sr or Ba) is nearly constant.
Complete the following chemical reactions.
(i) PbS(s) + H2O2(aq) →
(ii) MnO-4(aq) + H2O2(aq) →
(iii) CaO(s) + H2O(g) →
(iv) AlCl3(g) + H2O(I) →
(v) Ca3N2(s) + H2O(I) →
Classify the above into (a) hydrolysis, (b) redox and (c) hydration reactions.
Calculate the concentration of nitric acid in moles per litre in a sample which has a density, 1.41 g mL–1 and the mass per cent of nitric acid in it being 69%.
State as to why
(a) a solution of Na2CO3 is alkaline ?
(b) alkali metals are prepared by electrolysis of their fused chlorides ?
(c) sodium is found to be more useful than potassium ?