Class 12 Chemistry - Chapter Coordination Compounds NCERT Solutions | Explain the bonding in coordination comp
Explain the bonding in coordination compounds in terms of Werner’s postulates.
In order to explain the nature of bonding and structure of coordination compounds, Werner in 1893 proposed a theory called as Werner’s Coordination Theory. The postulates of theory are as follows:
1. In coordination compounds, metal atoms exhibit 2 types of valencies namely, primary and secondary valency. The primary valency is ionizable whereas the secondary valency is non- ionizable, i.e. primary valency corresponds to oxidation state and secondary valency corresponds to coordination number.
2. Every metal atom has a fixed number of secondary valencies i.e. fixed coordination number.
3. The metal atom tends to satisfy both its primary as well as secondary valencies. Primary valencies are satisfied by negative ions whereas secondary valencies are satisfied by negative or by neutral molecules.
4. The secondary valencies are always directed towards the fixed positions in space and this leads to definite geometry of the coordination compound. For example: if the metal ion has four secondary valencies, these are arranged in either tetrahedral or square planar arrangement around the central metal ion. The secondary valencies, thus, determine the stereochemistry of the complex.
More Questions From Class 12 Chemistry - Chapter Coordination Compounds
- Q:-
[NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
- Q:-
Explain on the basis of valence bond theory that [Ni(CN)4]2- ion with square planar structure is diamagnetic and the [Ni(CN)4]2- ion with tetrahedral geometry is paramagnetic.
- Q:-
Draw figure to show the splitting of d orbitals in an octahedral crystal field.
- Q:-
Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex:
(i) K[Cr(H2O)2(C2O4)2].3H2O
(ii) [Co(NH3)5Cl]Cl2
(iii) CrCl3(py)3
(iv) Cs[FeCl4]
(v) K4[Mn(CN)6]
- Q:-
The oxidation number of cobalt in K[Co(CO)4] is
(i) +1
(ii) +3
(iii) -1
(iv) -3
- Q:-
[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2- is diamagnetic. Explain why?
- Q:-
Discuss the nature of bonding in metal carbonyls.
- Q:-
Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i) [Fe(CN)6]4-
(ii) [FeF6]3-
(iii) [Co(C2O4)3]3-
(iv) [CoF6]3-
- Q:-
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
- Q:-
Predict the number of unpaired electrons in the square planar [Pt(CN)4]2- ion.
Popular Questions of Class 12 Chemistry
- Q:-
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
- Q:-
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
- Q:-
Why are solids rigid?
- Q:-
Write any two characteristics of Chemisorption.
- Q:-
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
- Q:-
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
- Q:-
Why are pentahalides more covalent than trihalides?
- Q:-
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
- Q:-
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
- Q:-
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Recently Viewed Questions of Class 12 Chemistry
- Q:-
Conductivity of 0.00241 M acetic acid is 7.896 × 10 - 5 S cm - 1. Calculate its molar conductivity and if Amº for acetic acid is 390.5 S cm2 mol - 1, what is its dissociation constant?
- Q:-
In a pseudo first order hydrolysis of ester in water, the following results were obtained:
t/s 0 30 60 90 [Ester]mol L - 1
0.55 0.31 0.17 0.085 (i) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(ii) Calculate the pseudo first order rate constant for the hydrolysis of ester.
- Q:-
Write the isomers of the compound having formula C4H9Br.
- Q:-
Giving examples, differentiate between 'roasting' and 'calcination'.
- Q:-
Calculate the molarity of each of the following solutions:
(a)30 g of Co(NO3)2. 6H2O in 4.3 L of solution
(b)30 mL of 0.5 M H2SO4 diluted to 500 mL.
- Q:-
An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens' reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.
- Q:-
Write IUPAC names of the following compounds:
- Q:-
Suggest the most important type of intermolecular attractive interaction in the following pairs.
(i) n-hexane and n-octane
(ii) I2 and CCl4
(iii) NaClO4 and water
(iv) methanol and acetone
(v) acetonitrile (CH3CN) and acetone (C3H6O).
- Q:-
Give IUPAC names of the following ethers:
- Q:-
Which meatal in the first series of transition metals exhibits +1 oxidationstate most frequently and why?
1 Comment(s) on this Question
Verry gooooooooooooooooooooood answerðððððððððððððððððððððâ¤â¤â¤â¤â¤â¤â¤â¤â¤ððððððððððð
- All Chapters Of Class 12 Chemistry
- All Subjects Of Class 12