Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Element |
General outer electronic configuration |
s–block(alkali metals) |
ns1–2, where n = 2 – 7 |
p–block(metals & non metals) |
ns2np1–6, where n = 2 – 6 |
d–block(transition elements) |
(n–1) d1–10 ns0–2, where n = 4 – 7 |
f–block(inner transition elements) |
(n–2)f1–14(n–1)d0–10ns2, where n = 6 – 7 |
Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F–
(ii) Ar
(iii) Mg2+
(iv) Rb+
What is the basic difference between the terms electron gain enthalpy and electronegativity?
Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is:
(a) B > C > Si > N > F
b) Si > C > B > N > F
(c) F > N > C > B > Si
d) F > N > C > Si > B
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
How does atomic radius vary in a period and in a group? How do you explain the variation?
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N
(b) F > O > Cl > N
(c) Cl > F > O > N
(d) O > F > N > Cl
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
Write the atomic number of the element present in the third period and seventeenth group of the periodic table.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040 (assume the density of water to be one).
What is the lowest value of n that allows g orbitals to exist?
Write bond line formulas for : Isopropyl alcohol, 2,3-Dimethyl butanal, Heptan-4- one.
Do you expect different products in solution when aluminium(III) chloride and potassium chloride treated separately with
(i) normal water
(ii) acidified water, and
(iii) alkaline water?
Write equations wherever necessary.
What are electron deficient compounds? Are BCl3 and SiCl4 electron deficient species? Explain.
Suggest reasons why the B-F bond lengths in BF3 (130 pm) and BF-4(143 pm) differ.
Which of the following represents the correct IUPAC name for the compounds concerned?
(a) 2,2-Dimethylpentane or 2-Dimethylpentane
(b) 2,4,7-Trimethyloctane or 2,5,7-Trimethyloctane
(c) 2-Chloro-4-methylpentane or 4-Chloro-2-methylpentane
(d) But-3-yn-1-ol or But-4-ol-1-yne
The solubility of Sr(OH)2 at 298 K is 19.23 g/L of solution. Calculate the concentrations of strontium and hydroxyl ions and the pH of the solution.
What causes the temporary and permanent hardness of water?
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Configuration of d-block is correctly given according to NCERT Book. Pd has the configuration of [Kr]5s^(0) 4d^(10), which justifies the given configuration.
General electronic configuration for d block is WRONG. It should be (n-1)d(1-10)ns(1-2)
General configuration of D block element is wrong. It is (n -1)d^1-10ns^1-2. This right general configuration of D block element
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