The increasing order of reactivity among group 1 elements is Li < Na < K < Rb CI > Br > I. Explain.
These elements belongs to s block with general electronic configuration ns1 group 1 elements are called as alkali metals and are radioactive in nature.The elements present in group 1 have only 1 valence electron, which they tend to lose. Group 17 elements, on the other hand, need only one electron to attain the noble gas configuration. On moving down group 1, the ionization enthalpies decrease due to their very large atomic size, as a result of which the valence s electron can be readily removed .These values decrease down the group because of decrease in the magnitude of force of attraction with the nucleus on account of increased atomic radii and magnitude of screening effect. Thus, the increasing order of reactivity among group 1 elements is as follows:
Li < Na < K < Rb < Cs
They are called halogens (sea salt producers). In group 17, as we move down the group from Cl to I, the fluorine is the most reactive and iodine is least reactive because these halogens have low dissociation energies, as a result they easily dissociate into atoms and react with other substances. Also the halogens have high electron affinity and can easily gain an electron. Thus, the decreasing order of reactivity among group 17 elements is as follows:
F > Cl > Br > I
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F–
(ii) Ar
(iii) Mg2+
(iv) Rb+
What is the basic difference between the terms electron gain enthalpy and electronegativity?
Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is:
(a) B > C > Si > N > F
b) Si > C > B > N > F
(c) F > N > C > B > Si
d) F > N > C > Si > B
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
How does atomic radius vary in a period and in a group? How do you explain the variation?
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N
(b) F > O > Cl > N
(c) Cl > F > O > N
(d) O > F > N > Cl
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
The Mn3+ ion is unstable in solution and undergoes disproportionation to give Mn2+, MnO2, and H+ ion. Write a balanced ionic equation for the reaction.
Discuss the principle of estimation of halogens, sulphur and phosphorus present in an organic compound.
For an isolated system, ΔU = 0, what will be ΔS?
Explain structures of diborane and boric acid.
The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists:
1. n = 4, l = 2, ml = –2 , ms = –1/2
2. n = 3, l = 2, ml= 1 , ms = +1/2
3. n = 4, l = 1, ml = 0 , ms = +1/2
4. n = 3, l = 2, ml = –2 , ms = –1/2
5. n = 3, l = 1, ml = –1 , ms= +1/2
6. n = 4, l = 1, ml = 0 , ms = +1/2
What are the major causes of water pollution? Explain.
Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same reaction yields 1-bromopropane. Explain and give mechanism.
Complete the following chemical reactions.
(i) PbS(s) + H2O2(aq) →
(ii) MnO-4(aq) + H2O2(aq) →
(iii) CaO(s) + H2O(g) →
(iv) AlCl3(g) + H2O(I) →
(v) Ca3N2(s) + H2O(I) →
Classify the above into (a) hydrolysis, (b) redox and (c) hydration reactions.
Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?
Among the following pairs of orbitals which orbital will experience the larger effective nuclear charge?
(i) 2s and 3s,
(ii) 4d and 4f,
(iii) 3d and 3p