What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F–
(ii) Ar
(iii) Mg2+
(iv) Rb+
Isoelectronic species/ions/atoms are the species which have same number of electrons but different magnitude of nuclear charges and belongs to different atoms or ions.The isoelctronic ions with greater nuclear charge will have small size as compared to the ion with smaller nuclear charge.
(i) F– ion has 9 + 1 = 10 electrons. Thus, the species isoelectronic with it will also have 10 electrons. Some of its isoelectronic species are Na+ ion (11 – 1 = 10 electrons), Ne (10 electrons), O2– ion (8 + 2 = 10 electrons), and Al3+ ion (13 – 3 = 10 electrons).
(ii) Ar has 18 electrons. Thus, the species isoelectronic with it will also have 18 electrons. Some of its isoelectronic species are S2– ion (16 + 2 = 18 electrons), Cl– ion (17 + 1 = 18 electrons), K+ ion (19 – 1 = 18 electrons), and Ca2+ ion (20 – 2 = 18 electrons).
(iii) Mg2+ ion has 12 – 2 = 10 electrons. Thus, the species isoelectronic with it will also have 10 electrons. Some of its isoelectronic species are F– ion (9 + 1 = 10 electrons), Ne (10 electrons), O2– ion (8 + 2 = 10 electrons), and Al3+ ion (13 – 3 = 10 electrons).
(iv) Rb+ ion has 37 – 1 = 36 electrons. Thus, the species isoelectronic with it will also have 36 electrons. Some of its isoelectronic species are Br– ion (35 + 1 = 36 electrons), Kr (36 electrons), and Sr2+ ion (38 – 2 = 36 electrons).
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
What is the basic difference between the terms electron gain enthalpy and electronegativity?
Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is:
(a) B > C > Si > N > F
b) Si > C > B > N > F
(c) F > N > C > B > Si
d) F > N > C > Si > B
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
How does atomic radius vary in a period and in a group? How do you explain the variation?
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N
(b) F > O > Cl > N
(c) Cl > F > O > N
(d) O > F > N > Cl
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
Write the atomic number of the element present in the third period and seventeenth group of the periodic table.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
The pH of 0.1M solution of cyanic acid (HCNO) is 2.34. Calculate the ionization constant of the acid and its degree of ionization in the solution.
Symbols can be written, whereas symbols
are not acceptable. Answer briefly.
A large number of fish are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish kill.
Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?
Explain why the following systems are not aromatic?
Explain the formation of H2 molecule on the basis of valence bond theory.
Give one method for industrial preparation and one for laboratory preparation of CO and CO2 each.
H3PO3 can be represented by structures 1 and 2 shown below. Can these two structures be taken as the canonical forms of the resonance hybrid representing H3PO3? If not, give reasons for the same.
Write the significance of a plus and a minus sign shown in representing the orbitals.
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