Why do we require artificial sweetening agents?
Diabetes mellitus is the third leading cause of death in the world. It is a clinical condition characterized by increased blood glucose level due to insufficient or inefficient INSULIN. Diabetes is a major cause of night blindness, renal failure, heart attacks, strokes and obesity. A diabetes patient is advised to consume low calories (i.e. low fat, carbohydrates and high protein fiber rich diet). Carbohydrates should be taken in the form of starches and complex sugars. The intake of refined sugars (sucrose, glucose) should be avoided. Therefore, artificial sweetening agents that do not add to the calorie intake of a person are required. Saccharin (500 times as sweet as sucrose), aspartame (a peptide 160 times sweeter than sucrose) are few examples of artificial sweeteners.
Why do soaps not work in hard water?
Explain the following terms with suitable examples
(i) cationic detergents
(ii) anionic detergents and
(iii) non-ionic detergents.
What are food preservatives ?
Sleeping pills are recommended by doctors to the patients suffering from sleeplessness but it is not advisable to take its doses without consultation with the doctor, Why?
How do antiseptics differ from disinfectants ? Give one example of each.
Why is use of aspartame limited to cold foods and drinks?
What are the main constituents of dettol?
With reference to which classification has the statement, ranitidine is an antacid been given?
Write the chemical equation for preparing sodium soap from glyceryl oleate and glyceryl palmitate. Structural formulae of these compounds are given below.
(i) (C15H31COO)3 C3H5 - Glyceryl palmitate
(ii)(C17H33COO)3 C3H5 - Glyceryl oleate
Name a substance which can be used as an antiseptic as well as disinfectant.
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
What is meant by 'disproportionation'? Give two examples of disproportionation reaction in aqueous solution.
Give the IUPAC names of the following compounds:
(i) CH3CH(Cl)CH(Br)CH3
(ii) CHF2CBrClF
(iii) ClCH2C≡CCH2Br
(iv) (CCl3)3CCl
(v) CH3C(p-ClC6H4)2CH(Br)CH3
(vi) (CH3)3CCH=CClC6H4I-p
What happens when
(i) n-butyl chloride is treated with alcoholic KOH,
(ii) bromobenzene is treated with Mg in the presence of dry ether,
(iii) chlorobenzene is subjected to hydrolysis,
(iv) ethyl chloride is treated with aqueous KOH,
(v) methyl bromide is treated with sodium in the presence of dry ether,
(vi) methyl chloride is treated with KCN.
Calculate the 'spin only' magnetic moment of M2+(aq) ion (Z = 27).
Q1 : Write down the electronic configuration of:
(i) Cr3+ (iii) Cu+ (v) Co2+ (vii) Mn2+
(ii) Pm3+ (iv) Ce4+ (vi) Lu2+ (viii) Th4+
For M2+/M and M3+/M2+ systems, the Eā values for some metals are as follows:
Cr2+/Cr -0.9V
Cr3/Cr2+ -0.4 V
Mn2+/Mn -1.2V
Mn3+/Mn2+ +1.5 V
Fe2+/Fe -0.4V
Fe3+/Fe2+ +0.8 V
Use this data to comment upon:
(i) The stability of Fe3+in acid solution as compared to that of Cr3+or Mn3+ and
(ii) The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
How do you explain the amphoteric behaviour of amino acids?
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.