Explain the following terms with suitable examples
(i) cationic detergents
(ii) anionic detergents and
(iii) non-ionic detergents.
(i) Cationic detergent
Cationic detergents are quaternary ammonium salts of acetates, chlorides, or bromides. These are called cationic detergents because the cationic part of these detergents contains a long hydrocarbon chain and a positive charge on the N atom.
For example: cetyltrimethylammonium bromide
(ii) Anionic detergents
Anionic detergents are of two types:
1.Sodium alkyl sulphates: These detergents are sodium salts of long chain alcohols. They are prepared by first treating these alcohols with concentrated sulphuric acid and then with sodium hydroxide. Examples of these detergents include sodium lauryl sulphate (C11H23CH2OSO3-Na+) and sodium stearyl sulphate (C17H35CH2OSO3-Na+).
2.Sodium alkylbenzenesulphonates: These detergents are sodium salts of long chain alkylbenzenesulphonic acids. They are prepared by Friedel-Crafts alkylation of benzene with long chain alkyl halides or alkenes. The obtained product is first treated with concentrated sulphuric acid and then with sodium hydroxide. Sodium 4-(1-dodecy) benzenesulphonate (SDS) is an example of anionic detergents.
(iii) Non-ionic detergents
Molecules of these detergents do not contain any ions. These detergents are esters of alcohols having high molecular mass. They are obtained by reacting polyethylene glycol and stearic acid.
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Sleeping pills are recommended by doctors to the patients suffering from sleeplessness but it is not advisable to take its doses without consultation with the doctor, Why?
How do antiseptics differ from disinfectants ? Give one example of each.
Why is use of aspartame limited to cold foods and drinks?
What are the main constituents of dettol?
With reference to which classification has the statement, ranitidine is an antacid been given?
Write the chemical equation for preparing sodium soap from glyceryl oleate and glyceryl palmitate. Structural formulae of these compounds are given below.
(i) (C15H31COO)3 C3H5 - Glyceryl palmitate
(ii)(C17H33COO)3 C3H5 - Glyceryl oleate
Name a substance which can be used as an antiseptic as well as disinfectant.
What are artificial sweetening agents? Give two examples.
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
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(i) 1-Bromo-1-methylcyclohexane
(ii) 2-Chloro-2-methylbutane
(iii) 2,2,3-Trimethyl-3-bromopentane.
Predict the products of the following reactions:
(i)
(ii)
(iii)
(iv)
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Discuss briefly giving an example in each case the role of coordination compounds in:
(i) biological system
(ii) medicinal chemistry
(iii) analytical chemistry
(iv) extraction/metallurgy of metals
Give four examples of heterogeneous catalysis.
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Give examples and suggest reasons for the following features of the transition metal chemistry:
(i)The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
(ii)A transition metal exhibits highest oxidation state in oxides and fluorides.
(iii) The highest oxidation state is exhibited in oxoanions of a metal.
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
formula for cationic detergent is wrong
I am happy
Kaint
It was really helpful ty for providing such such a nice answer
well defined..
The structure of cetyltrimethylammoniumbromide is wrong as cetyl carbons are not mentioned in structure there is only 2 carbons where cetyl should be Added
could you kindly give an example of cationic detergents with acetate heads?Just want to know how they are going to be stable with yet another acetate ion(its big no?) to carry...
Owsm