Is there any change in the hybridisation of B and N atoms as a result of the following reaction?
BF3 + NH3 → F3B.NH3
The atomic number of boron is 5 & its electronic configuration in ground state is 1s2 2s2 2p1, & in excited state is 1s2 2s1 2p2 , this means its one s & 2 p orbital will take part in hybridization to form sp2 hybrid orbital.
Similarly N atom has atomic number of 7, with electronic configuration of 1s2 2s2 2p3 in its ground state & in it excited state it has sp3 hybridization.
Now according to the question Boron & Nitrogen in reactant stage has sp2 & sp3 hybridization respectively, but on the product side an adduct is formed, wherein Boron has changed it s hybridization to sp3 while Nitrogen remains in same sp3 hybridization
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2, , HCOOH
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
Which one of the alkaline earth metal carbonates is thermally the most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
What would be the SI unit for the quantity pV2T 2/n?
Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
Justify that the following reactions are redox reactions:
(a) CuO(s) + H2(g) → Cu(s) + H2O(g)
(b) Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)
(c) 4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3 (s)
(d) 2K(s) + F2(g) → 2K+F– (s)
(e) 4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)
Dual behaviour of matter proposed by de Broglie led to the discovery of electron microscope often used for the highly magnified images of biological molecules and other type of material. If the velocity of the electron in this microscope is 1.6 × 106 ms–1, calculate de Broglie wavelength associated with this electron.
For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated :
(a) C4H8 (one double bond)
(b) C5H8 (one triple bond)
What are the common physical and chemical features of alkali metals?
Explain the significance of sodium, potassium, magnesium and calcium inbiological fluids.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
You explained but no one understands no offence
i dunno understand that ???
How can we find hybridization of F3B.NH3
There is no change in both the case for hybridisation. This statement is given in a guide.....Which one is true? Why?