Write the resonance structures for SO3, NO2 and .
Resonance is defined as the phenomenon as a result of which a molecule can be expressed in different forms, none of which can explain all the properties of the molecules. The actual structure of the molecule is called resonance hybrid.
The resonating structures must have same position of the atoms, they must have same number of paired & unpaired electrons, they should have nearlt same energy. The resonance structures are:
(a) SO3:
(b) NO2
(c)
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2, , HCOOH
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
What are the necessary conditions for any system to be aromatic?
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
Write reactions to justify amphoteric nature of aluminium.
Calculate the energy required for the process
The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1
Find energy of each of the photons which
(i) correspond to light of frequency 3× 1015 Hz.
(ii) have wavelength of 0.50 Å.
ΔU0of combustion of methane is – X kJ mol–1. The value of ΔH0 is
(i) = ΔU0
(ii) > ΔU0
(iii) < ΔU0
(iv) = 0
Give the IUPAC names of the following compounds:
Give a brief description of the principles of the following techniques taking an example in each case.
(a) Crystallisation
(b) Distillation
(c) Chromatography
What do you mean by green chemistry? How will it help decrease environmental pollution?
The reaction,
CO(g) + 3H2(g) ↔ CH4(g) + H2O(g)
is at equilibrium at 1300 K in a 1L flask. It also contain 0.30 mol of CO, 0.10 mol of H2 and 0.02 mol of H2O and an unknown amount of CH4 in the flask. Determine the concentration of CH4 in the mixture. The equilibrium constant, Kc for the reaction at the given temperature is 3.90.
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