Class 11 Chemistry - Chapter Chemical Bonding and Molecular Structure NCERT Solutions | Discuss the shape of the following molec
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Valence shell electron pair repulsion (VSEPR) theory:
It is a model used to predict the 3D geometry of individual molecules from the number of electron pairs surrounding their central atoms. It was developed by Gillespie & Nyholm. The various geometries are as follows according to number of lone pair present:
BeCl2:
The central atom has no lone pair and there are two bond pairs. i.e., BeCl2 is of the type EX2. Hence, it has a linear shape.
BCl3:
The central atom has no lone pair and there are three bond pairs. Hence, it is of the type EX3. Hence, it is trigonal planar.
SiCl4:
The central atom has no lone pair and there are four bond pairs. Hence, the shape of SiCl4 is tetrahedral being the EX4 type molecule.
AsF5:
The central atom has no lone pair and there are five bond pairs. Hence, AsF5 is of the type EX5. Therefore, the shape is trigonal bipyramidal.
H2S:
The central atom has one lone pair and there are two bond pairs. Hence, H2S is of the type AB2E. The shape is Bent.
PH3:
The central atom has one lone pair and there are three bond pairs. Hence, PH3 is of the EX5 type. Therefore, the shape is trigonal bipyramidal.
More Questions From Class 11 Chemistry - Chapter Chemical Bonding and Molecular Structure
- Q:-
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
- Q:-
Use molecular orbital theory to explain why the Be2 molecule does not exist.
- Q:-
Explain the formation of H2 molecule on the basis of valence bond theory.
- Q:-
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
- Q:-
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
- Q:-
Which out of NH3 and NF3 has higher dipole moment and why?
- Q:-
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
- Q:-
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
- Q:-
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2,
, HCOOH - Q:-
Which hybrid orbitals are used by carbon atoms in the following molecules?
(a)CH3–CH3;
(b) CH3–CH=CH2;
(c) CH3-CH2-OH;
(d) CH3-CHO
(e) CH3COOH
Popular Questions of Class 11 Chemistry
- Q:-
How do you account for the formation of ethane during chlorination of methane?
- Q:-
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
- Q:-
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
- Q:-
What are the common physical and chemical features of alkali metals?
- Q:-
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4 - Q:-
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
- Q:-
What is the basic theme of organisation in the periodic table?
- Q:-
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only. - Q:-
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure? - Q:-
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Recently Viewed Questions of Class 11 Chemistry
- Q:-
What are the major causes of water pollution? Explain.
- Q:-
Explain structures of diborane and boric acid.
- Q:-
Symbols
can be written, whereas symbols 
are not acceptable. Answer briefly. - Q:-
Write the conjugate acids for the following Brönsted bases: NH–2 , NH3 and HCOO–.
- Q:-
Similar to electron diffraction, neutron diffraction microscope is also used for the determination of the structure of molecules. If the wavelength used here is 800 pm, calculate the characteristic velocity associated with the neutron.
- Q:-
The solubility of Sr(OH)2 at 298 K is 19.23 g/L of solution. Calculate the concentrations of strontium and hydroxyl ions and the pH of the solution.
- Q:-
Write balanced equations for:
(i) BF3 + LiH →
(ii) B2H6 + H2O →
(iii) NaH + B2H6 →
(iv) H3BO3
(v) Al + NaOH →
(vi) B2H6 + NH3 →
- Q:-
Knowing the properties of H2O and D2O, do you think that D2O can be used for drinking purposes?
- Q:-
What is the pH of 0.001 M aniline solution? The ionization constant of aniline can be taken from Table 7.7. Calculate the degree of ionization of aniline in the solution. Also calculate the ionization constant of the conjugate acid of aniline.
- Q:-
How much time would it take to distribute one Avogadro number of wheat grains, if 1010 grains are distributed each second?
9 Comment(s) on this Question
Thank you
merci
Thank you
What is the shape of XeF4
XeF4. & SF6 shape
Plz explain, CH4 also
why CH4,NH3,H2O are not shown?
PH3 does not have trigonal bipyramidal shape rather it has trigonal pyramidal shape
shape ofch4
- All Chapters Of Class 11 Chemistry
- All Subjects Of Class 11