Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
For any compound to be water soluble, it should develop dipoles (partial negative and partial positive charges) at the two ends of compound. The development of charges results in the formation of hydrogen bond between the water molecule and the compound. The development of charges at two ends is due to the difference in the electronegativity between two atoms. The atom with higher electronegativity will acquire negative charge while the atom with lower electronegativity will acquire positive charge. A glucose molecule contains five –OH (highly electronegative) groups while a sucrose molecule contains eight −OH groups. Thus, glucose and sucrose undergo extensive H-bonding with water. Hence, these are soluble in water.
But cyclohexane and benzene do not contain −OH groups. They contain only carbon and hydrogen atoms, as a result the dipole developed is very weak in nature and hence the hydrogen bond formed is not strong. Hence, they cannot undergo H-bonding with water and thus are insoluble in water.
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
What are nucleic acids? Mention their two important functions.
Where does the water present in the egg go after boiling the egg?
How do you explain the amphoteric behaviour of amino acids?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
What are the characteristics of the transition elements and why are they called transition elements? Which of the d-block elements may not be regarded as the transition elements?
For M2+/M and M3+/M2+ systems, the Eā values for some metals are as follows:
Cr2+/Cr -0.9V
Cr3/Cr2+ -0.4 V
Mn2+/Mn -1.2V
Mn3+/Mn2+ +1.5 V
Fe2+/Fe -0.4V
Fe3+/Fe2+ +0.8 V
Use this data to comment upon:
(i) The stability of Fe3+in acid solution as compared to that of Cr3+or Mn3+ and
(ii) The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
Distinguish between the meaning of the terms adsorption and absorption. Give one example of each.
Comment on the statement that "colloid is not a substance but a state of substance".
For a reaction, A + B → Product; the rate law is given by, r = k [A]½ [B]2. What is the order of the reaction?
A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.
Discuss briefly giving an example in each case the role of coordination compounds in:
(i) biological system
(ii) medicinal chemistry
(iii) analytical chemistry
(iv) extraction/metallurgy of metals
A first order reaction takes 40 min for 30% decomposition. Calculate t1/2.
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
How do antiseptics differ from disinfectants ? Give one example of each.
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