Write the important structural and functional differences between DNA and RNA.
The structural differences between DNA and RNA are as follows:
DNA |
RNA |
||
1. |
The sugar moiety in DNA molecules is β-D-2 deoxyribose. |
1. |
The sugar moiety in RNA molecules is β-D-ribose. |
2. |
DNA contains thymine (T). It does not contain uracil (U). |
2. |
RNA contains uracil (U). It does not contain thymine (T). |
3. |
The helical structure of DNA is double-stranded. |
3. |
The helical structure of RNA is single-stranded. |
The functional differences between DNA and RNA are as follows:
DNA |
RNA |
||
1 |
DNA is the chemical basis of heredity. |
1 |
RNA is not responsible for heredity. |
2 |
DNA molecules do not synthesise proteins, but transfer coded message for the synthesis of proteins in the cells. |
2 |
Proteins are synthesised by RNA molecules in the cells. |
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
What are nucleic acids? Mention their two important functions.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Calculate the molarity of each of the following solutions:
(a)30 g of Co(NO3)2. 6H2O in 4.3 L of solution
(b)30 mL of 0.5 M H2SO4 diluted to 500 mL.
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.
What is the role of cryolite in the metallurgy of aluminium?
What is the basicity of H3PO4?
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.
Why is sulphuric acid not used during the reaction of alcohols with KI?
An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL-1, then what shall be the molarity of the solution?
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
The add cause difficulty in viewing the answer