What are essential and non-essential amino acids? Give two examples ofeach type.
Essential amino acids are required by the human body, but they cannot be synthesised in the body. They must be taken through food.
For example: valine and leucine
Non-essential amino acids are also required by the human body, but they can be synthesised in the body.
For example: glycine and alanine
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
What are nucleic acids? Mention their two important functions.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3- is weakly paramagnetic. Explain.
Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?
Describe some features of catalysis by zeolites.
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.
What happens when H3PO3 is heated?
Consider a certain reaction A → Products with k = 2.0 x 10-2 s-1. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1.0 mol L-1.
Name a substance which can be used as an antiseptic as well as disinfectant.
Explain why NH3 is basic while BiH3 is only feebly basic.
What is the significance of leaching in the extraction of aluminium?
Glycine is a essential amino acid not an non essential amino acid