Write one difference in each of the following:
(a) Multimolecular colloid and Associated colloid
(b) Coagulation and Peptization
(c) Homogeneous catalysis and Heterogeneous catalysis
OR
(a) Write the dispersed phase and dispersion medium of milk.
(b) Write one similarity between Physisorption and chemisorption.
(c) Wrtie the chemical method by which Fe(OH)3 sol is prepared from FeCl3.
(a) In Multimolecular colloid the atoms or molecules are held by weak vander walls forces and In associated colloid. They behave as normal electrolytes at low concentrations and colloidal only at high concentrations.
(b) The process of Changing the colloid particle in a solution in to insoluble precipitate by addition of suitable electrolyte is known as cogulation and conversion of freshly precipitated substance in to colloidal solution by shaking with the suitable electrolyte is called peptization
(c) In Homogenous catalysis the catalyst and reactant are in the same phase and In Hetrogeneous catalysis the catalyst is in different phase than are the reactants.
OR
(a) Milk is an emulsion in which both the dispersed phase and the dispersion medium are in liquid state. In milk, liquid fat is dispersed in water. So fat is the dispersed phase and water is the dispersion medium.
(b) Both are surface phenomenon.
(c) A colloidal solution of Fe[OH]3 is prepared when concentrated solution of ferric chloride is added drop wise to hot water.
FeCl3 + 3H2O → Fe[OH]3 + 3HCl
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
If NaCl is doped with 10-3mol % of SrCl2, what is the concentration of cation vacancies?
Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
What type of stoichiometric defect is shown by:
(i) ZnS
(ii) AgBr
How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom
(i) Methyl benzoate (ii) m-Nitrobenzoic acid
(iii) p-Nitrobenzoic acid (iv) Phenylacetic acid
(v) p-Nitrobenzaldehyde.
A first order reaction takes 40 min for 30% decomposition. Calculate t1/2.
Give IUPAC names of the following ethers:
In terms of band theory, what is the difference
(i) Between a conductor and an insulator
(ii) Between a conductor and a semiconductor
Write the Nernst equation and emf of the following cells at 298 K:
(i) Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)
(ii) Fe(s) | Fe2+(0.001M) || H+(1M)|H2(g)(1bar) | Pt(s)
(iii) Sn(s) | Sn2+(0.050 M) || H+(0.020 M) | H2(g) (1 bar) | Pt(s)
(iv) Pt(s) | Br2(l) | Br-(0.010 M) || H+(0.030 M) | H2(g) (1 bar) | Pt(s).
Give plausible explanation for each of the following:
(i) Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
(ii) There are two -NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
(iii) During the preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, the water or the ester should be removed as soon as it is formed.
Can PCl5 act as an oxidising as well as a reducing agent? Justify.
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3- is weakly paramagnetic. Explain.