Write one difference between each of the following:
(a) Multimolcular colloid and macromolecular colloid
(b) Sol and gel
(c) O/W emulsion and W/O emulsion
(a) Multimolcular colloid and macromolecular colloid
Multimolcular colloid | Macromolecular colloid |
They are formed by the aggregation of large no. of atoms or molecule having diameter less than 1nm, e.g. sols of gold | They are molecules of large size. e.g. Polymers like rubber. |
(b) Sol and gel
Sol | gel |
The colloidal system in which dispersed phase = Solid The colloidal system in which dispersion medium = Liquid e.g. Muddy water, paints, cell fluids |
The colloidal system in which dispersed phase = Liquid The colloidal system in which dispersion medium = Solid e.g. Jellies, butter and cheese. |
(c) O/W emulsion and W/O emulsion
O/W emulsion | W/O emulsion |
An emulsion in which dispersed phase = Oil An emulsion in which dispersed phase = Water e.g. Vanishing Cream, Milk. |
An emulsion in which dispersed phase = Water An emulsion in which dispersed phase = Oil e.g. Butter and cold cream |
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
If NaCl is doped with 10-3mol % of SrCl2, what is the concentration of cation vacancies?
What is the effect of temperature on the rate constant of a reaction? How can this temperature effect on rate constant be represented quantitatively?
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
2.0 × 10 - 2 |
II | -- | 0.2 |
4.0 × 10 - 2 |
III | 0.4 | 0.4 | -- |
IV | -- | 0.2 |
2.0 × 10 - 2 |
Predict the products of electrolysis in each of the following:
(i) An aqueous solution of AgNO3 with silver electrodes.
(ii) An aqueous solution of AgNO3with platinum electrodes.
(iii) A dilute solution of H2SO4with platinum electrodes.
(iv) An aqueous solution of CuCl2 with platinum electrodes.
To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.
How are vitamins classified? Name the vitamin responsible for thecoagulation of blood.
The decomposition of NH3on platinum surface is zero order reaction. What are the rates of production of N2and H2if k = 2.5 x 10-4mol-1L s-1?
A solution of [Ni(H2O)6]2+ is green but a solution of [Ni(CN)4]2- is colourless. Explain.
Write the order of thermal stability of the hydrides of Group 16 elements.
Why copper matte is put in silica lined converter?
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?